It is not quite certain that this test measures the actual
“hardness” of the glass, but it affords some information as to its
power of resisting abrasion, and for many purposes this power is the
important factor.
Hardness being, as indicated above, a somewhat indefinite term, it
is not possible to give any precise statement as to the influence of
chemical composition upon the hardness of glass. In general terms it
may be said that glasses rich in silica and lime will be found to be
hard, while glasses rich in alkali, lead or barium, are likely to be
soft. It must, however, be borne in mind that rapid cooling, or even
the lack of careful annealing, will produce a very great increase of
hardness in even the softest glasses. The actual behaviour of a given
specimen of glass will, therefore, depend at least as much upon the
nature of the processes which it has undergone as upon its chemical
composition.
_The Thermal Properties of Glass_, although not of such general
importance as the mechanical properties, are yet of considerable
interest in a large number of the practical uses to which glass is
constantly applied. Perhaps the most important of these properties
is that known as thermal endurance, which measures the amount of
sudden heating or cooling to which glass may be exposed without risk
of fracture; the chimneys employed in connection with incandescent
gas burners, boiler gauge glasses, laboratory vessels, and even table
and domestic utensils are all exposed at times to sudden changes of
temperature, and in many cases the value of the glass in question
depends principally upon its power of undergoing such treatment without
breakage. The property of “thermal endurance” itself depends upon a
considerable number of more or less independent factors, and their
influence will be readily understood if we follow the manner in which
sudden change of temperature produces stress and, sometimes, fracture
in glass objects. If we suppose a hot liquid to be poured into a cold
vessel, the first effect upon the material of the vessel will be to
raise the temperature of the inner surface. Under the influence of
this rise of temperature the material of this inner layer expands,
or endeavours to expand, being restrained by the resistance of the
central and outer layers of material which are still cold; the result
of this contest is, that while the inner layer is thrown into a state
of compression, the outer and central layers are thrown into a state
of tension. Accordingly, if the tension so produced is sufficiently
great, the outer layers fracture under tension and the whole vessel is
shattered by the propagation of the crack thus initiated. From this
description of the process it will be seen that a high coefficient of
expansion and a low modulus of elasticity will both favour fracture,
while high tensile strength will tend to prevent it. The thermal
conductivity of the glass will also affect the result, because the
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