Thermal expansion is a vital factor in yet another of the uses of
glass. Our ordinary instrument for measuring temperature--the mercury
thermometer--is very considerably affected by the expansive behaviour
of glass. When a mercury thermometer is warmed the mercury column rises
in the stem because the mercury expands upon warming to a greater
extent than the glass vessel, bulb and stem, in which it is contained.
The subject of the graduations and corrections of the mercury glass
thermometer is a very large one and somewhat outside the scope of the
present volume; but attention should be drawn in this place to the
peculiarities of the behaviour of glass that have been discovered in
this connection. One of these is that when first blown the bulb of a
thermometer takes a very considerable time to acquire its final volume,
the result being, that if a freshly made thermometer is graduated,
after some time the zero of the instrument will be found considerably
changed, generally in a direction which indicates that the volume of
the bulb has slightly increased. By a special annealing or “ageing”
process this change can be completed in a comparatively short time
before the instrument is graduated. There is, however, a further
peculiarity which is prominent in some thermometers, although very
greatly reduced in the best modern glasses. This becomes apparent in
a decided change of zero whenever the thermometer has been exposed for
any length of time to a high temperature, the zero gradually returning
more or less to its original position in the course of time. With
thermometers made of glasses liable to these aberrations, the reading
for a given temperature depended largely upon the immediate past
history of the instrument; but, thanks to the Jena Works, thermometer
glasses are now available which are almost entirely free from this
defect. In this connection the curious fact has been observed that
glass containing both the alkalies (potash and soda) shows these
thermal effects much more markedly than a glass containing one of the
alkalies only.
_The thermal conductivity_ of glass, except in so far as it affects
the thermal endurance, is not a matter of any great direct practical
importance, although the fact that glass is always a comparatively poor
conductor of heat is utilised in many of its applications, as, for
example, the construction of conservatories and hot-houses, although
even in that case the opacity of glass to thermal radiations of long
wave-lengths is of more importance than its low thermal conductivity.
Similar statements apply, in a still more marked degree, to the subject
of the specific heat of glass.
Public-domain text, read in full here on John Shaqi.
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