_Lead_ is one of the most widely-used ingredients of glass; the glasses
containing this substance in notable quantity are all characterised to
a greater or less degree by similar properties, such as considerable
density and high refractive power, and are classed together under the
name “flint glasses.” Lead is now almost universally introduced into
glass mixtures in the form of red lead, although the other oxides of
lead might be employed almost equally well. Red lead is a mixture
of two oxides of lead (PbO and Pb_{2}O_{3}) in approximately such
proportions as to correspond to the formula Pb_{3}O_{4}. It is prepared
by the roasting of metallic lead in suitable furnaces, where the molten
lead is exposed to currents of hot air. The product is obtainable in
considerable purity, very small proportions of silica, derived from the
furnace bed, and of iron derived from the tools with which the lead is
handled, being the principal foreign substances found in good red lead.
Silver would be an objectionable impurity, but owing to the modern
perfect methods of de-silvering lead, that element is rarely found in
lead products. Analytical control of red lead as used in the glass
mixtures, and consequent adjustments of the mixture, are, however,
necessary where exact constancy in the glass produced is desired. The
reason for this necessity lies in the fact that the oxygen content, and
therefore the lead-oxide (PbO) content, varies decidedly from batch to
batch, while the material as actually delivered and used frequently
contains notable proportions of moisture.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account