The intimate resemblance between vitreous bodies and true liquids
is further emphasised when it is realised that true liquids can in
many instances pass into the vitreous state without undergoing any
critical change or exhibiting any discontinuity of behaviour, such as
is exhibited during the freezing of a crystalline body. In the latter
class of substances the passage from the liquid to the crystalline
state takes place at one definite temperature, and the change is
accompanied by a considerable evolution of heat, so that the cooling of
the mass is temporarily arrested. In the case of glasses, on the other
hand, the passage from the liquid to the apparently solid condition is
gradual and perfectly continuous, no evolution of heat or retardation
of cooling being observed even by the aid of the most delicate
instruments. We are thus justified in speaking of glasses as “congealed
liquids,” the process of congealing in this case involving no change
of structure, no re-arrangement of the molecules, but simply implies a
gradual stiffening of the liquid until the viscosity becomes so great
that the body behaves like a solid. It is, however, just this power
of becoming exceedingly stiff or viscous when cooled down to ordinary
temperatures that renders the existence of vitreous bodies possible.
All glasses are capable of undergoing the change to the crystalline
state when kept for a sufficient time at a suitable temperature. The
process which then takes place is known as “devitrification,” and
sometimes gives rise to serious manufacturing difficulties.
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