Gunnery in 1858: Being a Treatise on Rifles, Cannon, and Sporting Arms: Explaining the Principles of the Science of Gunnery, and Describing the Newest Improvements in Fire-Arms — John Shaqi
Gunnery in 1858: Being a Treatise on Rifles, Cannon, and Sporting Arms: Explaining the Principles of the Science of Gunnery, and Describing the Newest Improvements in Fire-ArmsGreener, William
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Gunnery in 1858: Being a Treatise on Rifles, Cannon, and Sporting Arms: Explaining the Principles of the Science of Gunnery, and Describing the Newest Improvements in Fire-Arms
Greener, William
Firearms; Gunnery
We thus perceive how analysis bears upon the case. We can see by such
reasoning on the subject, that, theoretically, there can be but _one set
of proportions calculated to produce the best and strongest gunpowder_,
and that those proportions must depend upon the established and unerring
laws of nature. The proportions, then, for gunpowder, by these
considerations, will be those in which the carbon will just consume the
oxygen of the nitre, and combine with the sulphur as much as will
exactly saturate the potassium. This will be effected by an atom each of
nitre and sulphur, and three atoms of carbon; or nitre 75·5, charcoal
18·8, and of sulphur 11·8.
In the present improved state of chemical science, when the nature of
the bodies comprising gunpowder is so well known, as well as the
compounds resulting from their action on each other, the proportions we
have named may be taken as the best for practice.
The charcoal should, in particular, not be less than the nitre, as the
smallest portion less than the whole atom would be the same as to leave
out the whole atom, in which case there would be no carbonic oxide
formed. If, for example, instead of the proportions of nitre 75·5,
charcoal 16·2, sulphur 15, the carbon were 16, then there would be 4·2
of carbon left in the residuum, and no carbonic oxide would be formed,
since bodies cannot unite but in definite proportions.
From these considerations we can perceive the reason why a small
proportion of carbonic oxide is always formed during the decomposition
of nitre by charcoal; for it will be evident, that as the nitric acid
contains five atoms of oxygen, four of these must combine with two atoms
of carbon to form two atoms of carbonic acid, while the _odd atom of
oxygen_ is compelled to take another atom to form carbonic oxide. But
this is not the case in the combustion of gunpowder, as carbonic acid
and nitrogen are the principal gases generated.
These proportions differ from any other formula yet prescribed; and,
though different in a great degree from the proportions laid down by
various writers on the subject, the reasons which are here given, as has
been seen, are such as carry with them a conviction of their truth: for
there cannot possibly be any benefit arising from a greater quantity of
any of these materials than is absolutely necessary to form the
composition in question; and if the smallest quantity be above what is
requisite to consume the whole, that, however small it may be, is highly
detrimental to the effective energy of the mass. What we may here call
clean gunpowder, such as may be used with confidence for repeated
discharges of fire-arms of any description, is of the greatest
importance; therefore, it does not appear to us, that any given
proportions are so likely to accomplish that object as those before
specified.
TABLE OF COMPOSITION OF DIFFERENT GUNPOWDERS.
Public-domain text, read in full here on John Shaqi.
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