Gunpowder and Ammunition, Their Origin and ProgressHime, H. W. L. (Henry William Lovett)
History
Gunpowder and Ammunition, Their Origin and Progress
Hime, H. W. L. (Henry William Lovett)
Ammunition; Gunpowder
A clue to the composition of the Kallinikos mixture may perhaps be
found in its Greek name, “sea-fire” or “wet-fire.” One substance
had long been known with whose combustion water was closely
connected—quicklime, and with its properties Kallinikos, as an
architect, must have been perfectly familiar. Its temperature rises—to
150° C. (302° F.) if the quantity be large—when sprinkled with water,
and it can consequently be employed to ignite substances with low
points of ignition. For example, if a mixture of quicklime and naphtha
be thrown into water, the rapid rise in temperature of the lime causes
a sudden and strong development of vapour from the naphtha, which on
mixing with the air becomes highly explosive. Such a mixture, it is
almost unnecessary to add, could not be handled with safety _after_ it
has been wet. Plutarch was aware of the explosive nature of naphtha
vapour. “Naphtha,” he says, “is like bitumen, and is so easy to set
on fire that, without touching it with any flame, it will catch light
from the rays which are sent forth from a fire, burning the air which
is between both.”[74] Pliny speaks of the heat developed by quicklime
when sprinkled with water. “It is strange,” he says, “that what has
already been burnt should be ignited by water” (_mirum aliquid,
postquam arserit, accendi aquis_).[75] The same property is implicitly
referred to in the “Kestoi,” attributed to Sextus Julius Africanus
of Emaus, who lived under Alexander Severus, 222-235. The military
portions of this work, however, must have been written long afterwards,
in the end of the sixth or the beginning of the seventh century at the
earliest; for Belisarius, who was born in 505, is mentioned in the
sixty-sixth chapter.[76] In the forty-fifth chapter there is a recipe
for a quicklime-asphalt composition, which is called “automatic fire.”
This mixture was used by jugglers to exhibit “spontaneous combustion,”
a little water being secretly poured on a plate on which a ball of
the composition was placed.[77] It contained very little quicklime
(παντελῶς ὀλίγον). Cameniata tells us that at the storming of Salonika
in 904 the Moslems threw “pitch and torches and quicklime” over the
walls.[78] By “quicklime” he probably meant the earthenware hand
grenades, filled with wet quicklime, described by the Emperor Leo,
who then sat on the throne (886-911). “The vapour of the quicklime,”
he says, “when the pots are broken, stifles and chokes the enemy and
distracts his soldiers.”[79]
The simplest and most probable explanation of the nature of the
sea-fire then is, that it was a sulphur-quicklime-naphtha mixture of
the same family as those shown in the following Table.
TABLE III.
_Sea-Fires._
Public-domain text, read in full here on John Shaqi.
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