Harper's Electricity Book for BoysAdams, Joseph H. (Joseph Henry)
Science
Harper's Electricity Book for Boys
Adams, Joseph H. (Joseph Henry)
Electricity -- Juvenile literature
The current, passing out of the cell from the carbon (C), is regulated
through the resistance-coils (R) by the switch (S). From thence it
passes to the rod from which the anode (A) is suspended, across the
electrolyte (E) to the kathode (K), on which the metal is deposited, and
then returns through the negative wire to the zinc (Z) in the cell. If
the hot bath is used the gold solution may be contained in a glazed
earthen jar or a porcelain-lined metal jar or kettle. But if the latter
is used care must be taken to see that none of the enamel is chipped, or
a short-circuit will be established between the rods. This jar or kettle
may then be placed on a gas-stove, and a thermometer should be
suspended so that the mercury bulb is half an inch below the surface of
the liquid, as shown at T in Fig. 13. As the liquid simmers or
evaporates away a little water should be added from time to time to keep
the bulk of the liquid up to its normal or original quantity.
[Illustration: FIG. 13]
Nickel-plating
The nickel-plating process is similar, in a general way, to the others;
it is carried on in a cold bath--that is, at the normal temperature,
without being heated or chilled artificially.
There are a great many formulæ for the nickel as well as for the other
baths, but the generally accepted one is composed of double nickel
ammonium-sulphate, three parts; ammonium carbonate, three parts; and
water, one hundred parts. Another good one is composed of nickel
sulphate, nitrate, or chloride, one part; sodium bisulphate, one part;
and water, twenty parts.
Nickel anodes are used in bath to maintain the strength, and great care
must be taken to have the bath perfectly balanced--that is, not too acid
nor too alkaline.
To test this, have some blue-and-red litmus paper. If the blue paper is
dipped in an acid solution, it will turn red; and back to blue again if
placed in an alkaline solution. If the nickel solution is too strong
with alkali, a trifle more of the nickel salts must be added, so that
both the red-and-blue litmus paper, when dipped in the liquid, will not
change color. If the bath is too alkaline, it will give a disagreeable
yellowish color to the deposit of metal on the kathode; and if too acid,
the metal will not adhere properly to the kathode, and will strip, peel,
or blister off.
Finishing
When the articles have been plated they will have a somewhat different
appearance to what may have been expected. For instance, copper-plated
articles will have a bright fleshy-pink hue; silver, an opaque
creamy-white; gold, a dead lemon-yellow color, and nickel much the
appearance of the silver, but slightly bluer in its tone. Articles
removed from the bath should be shaken over the bath so as to remove
the solution; then they should be immediately plunged into hot water,
rinsed thoroughly, and allowed to dry slowly.
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