Chemists have proved that no substance is sensitive to light when
perfectly pure and kept by itself in a dry place. If silver chloride is
placed in a glass tube, the air exhausted, and the tube hermetically
sealed, it may be exposed to sunlight, and will remain unchanged in
color.
The action of light on the silver chloride is to separate the chlorine
from the silver, but there must be some substance with which the
chlorine will combine, or the light will not decompose the chloride.
(Decompose is to separate the parts composing a compound body.)
For purposes of photography some substance must be used which will
combine very quickly with the silver, and such a substance is found in
silver nitrate. The chlorine set free by the action of light combines at
once with the pure silver in the nitrate of silver. The chemical nature
of the dark-colored substance produced by the action of light on the
silver chloride is not yet fully determined, but most chemists agree
that the silver chloride, when decomposed by light, produces silver
sub-chloride and chlorine. (A sub-chloride is a chloride which contains
more of the base than the acid. A molecule of silver chloride contains
one atom of silver and one of chlorine, while a molecule of sub-chloride
contains _two_ atoms of silver and one atom of chlorine.)
This silver chloride is white, but passes through different shades of
coloring, from a reddish-violet to a deep purplish-black, according to
the length of time it is exposed to the light.
When paper coated with a sensitive silver solution is placed under a
negative and exposed to the sun, the light reaches the paper through
different degrees of thickness, or density, in the gelatine film. In the
part of the negative which represents the sky the film is quite thick,
while in the part which represents the deep shadows it is thin,
sometimes being almost transparent. The part of the paper which is under
the portion of the negative representing the sky is scarcely affected by
the light, but in that part representing the shadows the light acts at
once, and quickly decomposes the silver chloride. When the paper is
taken from the printing-frame it contains different grades of the
deposit formed by the action of light on the silver chloride.
NOTE.--The first article in the series of "Chemistry of
Photography" was published in No. 867 (June 9). This article was on
the chemical elements, and contained the following paragraph:
Public-domain text, read in full here on John Shaqi.
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