Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
Science
Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
In the simplest form of cell, as zinc, copper, and dilute sulphuric acid,
no attempt has been made to prevent the evil of polarization, hence, it
will quickly polarize when the current is closed for any length of time,
and may be classified as an open circuit cell.
When polarization is remedied by chemical means, the chemical added is one
that has a strong affinity for hydrogen and will combine with it, thus
preventing the covering of the negative plate with the hydrogen gas.
[Illustration: FIGS. 42 and 43.--Carbon cell and carbon cylinder. Carbon
possesses a natural power to prevent a limited amount of polarization by
absorbing the hydrogen gas coming from the zinc rod; hence it is used in
various shapes for open circuit cells, which gives rise to as many
different names, such as _Samson_, _Hercules_, _Law_, _National_,
_Standard_, etc. In all these types of cell, sal-ammoniac and zinc are
used, and by corrugating the carbon, fluting it, or making concentric
cylinders, special merits are obtained in each case. The carbon element is
usually made in the form of a porous cup, filled with oxide of manganese
to prevent polarization, and then sealed. The zinc rod is inserted through
a porcelain insulator. About 4 to 6 ounces of sal-ammoniac are generally
used for cells of ordinary size. The salt is placed in the jar, water
poured in until it is about two-thirds full, and then stirred till all the
salt is dissolved. When the carbon cylinder is inserted, the solution
should be within 1-1/2 inches of the top of the jar. The electromotive
force is from 1.0 to 1.4 volts for the different forms of carbon cell.]
=Ques. What is a depolarizer?=
Ans. A substance employed in some types of cell to combine with the
hydrogen which would otherwise be set free at the positive electrode and
cause polarization.
The chemical used for this purpose may be either in a _solid_ or
_liquid_ form, which gives rise to several types of cell, such
as cells with a single fluid, containing both the acid and the
depolarizer, cells with a single exciting fluid and a solid
depolarizer, and cells with two separate fluids.
In the two fluid cell, the zinc is immersed in the liquid
(frequently dilute sulphuric acid) to be decomposed by the
action upon it, and the negative plate is surrounded by the
liquid depolarizer, which will be decomposed by the hydrogen gas
it arrests, thereby preventing polarization.
In _open circuit cells_ polarization does not have much opportunity to
occur, since the circuit is closed for such a short period of time; hence,
these cells are always ready to deliver a strong current when used
intermittently.
In _closed circuit cells_ polarization is prevented by chemical action, so
that the current will be constant and steady till the energy of the
chemicals is expended.
=Ques. What is a depolarizer bag?=
Public-domain text, read in full here on John Shaqi.
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