Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applicationsHawkins, N. (Nehemiah)
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Hawkins Electrical Guide v. 01 (of 10): Questions, Answers, & Illustrations, A progressive course of study for engineers, electricians, students and those desiring to acquire a working knowledge of electricity and its applications
Hawkins, N. (Nehemiah)
Electrical engineering -- Handbooks, manuals, etc.
The positive element is zinc, and the negative element black oxide of
copper. The exciting fluid is a solution of caustic potash. The black
oxide of copper plates are suspended from the cover of the jar by a light
framework of copper, one end of which forms the positive pole of the
battery. A zinc plate is suspended on each side of the copper oxide
element and kept from coming in contact with the latter by means of
vulcanite buttons.
When the cell is in action, the water is decomposed, and the oxygen thus
liberated combines with the zinc and forms oxide of zinc, which combines
with the potash to form a double salt of zinc and potash. The last
combination dissolves as rapidly as it is formed. The hydrogen liberated
by the decomposition of the water reduces the copper oxide to pure
metallic copper. It is highly important that the copper oxide plates be
completely submerged in the solution of caustic potash, and that heavy
paraffin oil be poured on top of the solution to the depth of about 1/4 of
an inch to exclude the air. If oil be not used, the formation of creeping
salts will reduce the life of the battery fully two-thirds. The battery
has a low electromotive force, about 0.7 of a volt, but as the internal
resistance is also very low, quite a large current can be drawn from the
cell.
The _Bunsen Cell_, shown in figs. 49 and 50, is a two fluid cell
constructed with zinc and carbon electrodes. The negative plate is carbon,
the positive plate amalgamated zinc. The excitant is a dilute solution of
sulphuric acid. The top part of the carbon is sometimes impregnated with
paraffin (to keep the acid from creeping up).
The force of the Bunsen cell increases after setting up for about an hour,
and the full effect is not attained until the acid soaks through the
porous cell. Carbons are not affected and last any length of time. The
zinc is slowly consumed through the mercury coating.
=Grenet Bichromate Cell.=--In this cell, as shown in figs. 49 and 50, the
positive element is zinc and the negative element carbon. The electrolyte
is a solution of bichromate of potash in a mixture of sulphuric acid and
water.
Public-domain text, read in full here on John Shaqi.
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