Heads of Lectures on a Course of Experimental Philosophy: Particularly Including Chemistry — John Shaqi
Heads of Lectures on a Course of Experimental Philosophy: Particularly Including ChemistryPriestley, Joseph
Philosophy
Heads of Lectures on a Course of Experimental Philosophy: Particularly Including Chemistry
Priestley, Joseph
Chemistry -- Early works to 1800
Dephlogisticated air is something heavier than atmospherical air, and
the purity of it measured by mixing with it two equal quantities of
nitrous or inflammable air, deducing the residuum after the diminution
from the three measures employed, and dividing the remainder by 3, as in
the process for common air.
_Of Phlogisticated Air._
The other ingredient in the composition of atmospherical air is
phlogisticated air. It is procured by extracting the dephlogisticated
part of the common air, as by the calcination of metals, &c. &c. by
dissolving animal substances in nitrous acid, and also by the union of
phlogiston with nitrous air, as by heating iron in it, and by a mixture
of iron-filings and sulphur.
Phlogisticated air extinguishes a candle, is entirely unfit for
respiration, and is something lighter than common air. It is not capable
of decomposition, except by exploding it together with a superabundance
of dephlogisticated air, and a quantity of inflammable air, or by taking
the electric spark repeatedly in a mixture of it and dephlogisticated
air. In these cases nitrous acid is formed.
LECTURE V.
_Of Inflammable Air._
Inflammable air is procured from all combustible substances by means of
heat and water, and from several of the metals, especially iron, zink,
and tin, by the vitriolic and marine acids.
From oils and spirit of wine it is procured by the electric spark. By
the same means also alkaline air is converted into it.
That which is procured from metals, especially by steam, is the purest
and the lightest, about ten times lighter than common air; in
consequence of which, if a sufficient quantity be confined in a light
covering, it is possible to make it carry up heavy weights.
When it is procured from animal or vegetable substances, it is of a
heavier kind, and burns with a lambent flame, of various colours,
according to the circumstances.
Calces of metals heated in inflammable air are revived, and the air
absorbed; and since all the metals are revived in the same inflammable
air, the principle of metallization, or _phlogiston_, appears to be the
same in them all.
Pure inflammable air seems to consist of phlogiston and water, and the
lambent kinds to be the same thing, with the addition of some oily
vapour diffused through it.
LECTURE VI.
_Of Nitrous Air._
Nitrous air is procured by dissolving most of the metals, especially
iron, mercury, and copper, in the nitrous acid; but that from mercury
seems to be the purest. Nitrous air produced from copper contains a
mixture of phlogisticated air. Some nitrous air is also obtained from
the solution of all vegetable substances in nitrous acid; whereas animal
substances in the same process yield chiefly phlogisticated air: but in
both these cases there is a mixture of fixed air.
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