Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But even during the lifetime of its founder this theory was opposed and
opposed by the logic of facts. In 1787 Berthollet published an account of
experiments on prussic acid,--the existence and preparation (from Prussian
blue) of which acid had been demonstrated three or four years before by the
Swedish chemist Scheele--which led him to conclude this compound to be a
true acid, but free from oxygen. In 1796 the same chemist studied the
composition and properties of sulphuretted hydrogen, and pronounced this
body to be an acid containing no oxygen.
But the experiments and reasoning of Berthollet were hidden by the masses
of facts and the cogency of argument of the Lavoisierian chemists.
The prevalent views regarding acids and bases were greatly strengthened by
the earlier researches of Sir Humphry Davy, in which he employed the
voltaic battery as an instrument in chemical investigation. Let us now
consider some of the electro-chemical work of this brilliant chemist.
In the spring of the year 1800 the electrical battery, which had recently
been discovered by Volta, was applied by Nicholson and Carlisle to effect
the decomposition of water. The experiments of these naturalists were
repeated and confirmed by Davy, then resident at Bristol, who followed up
this application of electricity to effect chemical changes by a series of
experiments extending from 1800 to 1806, and culminating in the Bakerian
Lecture delivered before the Royal Society in the latter year.
The history of Davy's life during these years, years rich in results of the
utmost importance to chemical science, will be traced in the sequel;
meanwhile we are concerned only with the results of his chemical work.
The first Bakerian Lecture of Humphry Davy, "On some Chemical Agencies of
Electricity," deserves the careful study of all who are interested in the
methods of natural science; it is a brilliant example of the
disentanglement of a complex natural problem.
Volta and others had subjected water to the action of a current of
electricity, and had noticed the appearance of acid and alkali at the
oppositely electrified metallic surfaces. According to some experimenters,
the acid was nitrous, according to others, muriatic acid. One chemist
asserted the production of a new and peculiar body which he called _the
electric acid_. The alkali was generally said to be ammonia.
When Davy passed an electric current through distilled water contained in
glass vessels, connected by pieces of moist bladder, cotton fibre, or
other vegetable matters, he found that nitric and hydrochloric acids were
formed in the water surrounding the positively electrified plate or pole,
and soda around the negatively electrified pole, of the battery.
Public-domain text, read in full here on John Shaqi.
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