Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
I think that our knowledge of salt is now more complete than our knowledge
of either acid, alkali, or earth. We know that a salt is formed by the
union of an acid and an alkali or earth; if, then, we get to know the
composition of acids and bases (_i.e._ alkalis and earths), we shall be
well on the way towards knowing the composition of salts.
And now we must resume our story where we left it at p. 176. Lavoisier had
recognized oxygen as the acidifier; Black had proved that a caustic alkali
does not contain carbonic acid.
Up to this time metallic calces, and for the most part alkalis and earths
also, had been regarded as elementary substances. Lavoisier however proved
calces to be compounds of metals and oxygen; but as some of those calces
had all the properties which characterized earths, it seemed probable that
all earths are metallic oxides, and if all earths, most likely all alkalis
also. Many attempts were made to decompose earths and alkalis, and to
obtain the metal, the oxide of which the earth or the alkali was supposed
to be. One chemist thought he had obtained a metal by heating the earth
baryta with charcoal, but from the properties of his metal we know that he
had not worked with a pure specimen of baryta, and that his supposed
metallic base of baryta was simply a little iron or other metal, previously
present in the baryta, or charcoal, or crucible which he employed.
But if Lavoisier's view were correct--if all bases contained oxygen--it
followed that all salts are oxygen compounds. Acids all contain oxygen,
said Lavoisier; this was soon regarded as one of the fundamental facts of
chemistry. Earths and alkalis are probably oxides of metals; this before
long became an article of faith with all orthodox chemists. Salts are
produced by the union of acids and bases, therefore all salts contain
oxygen: the conclusion was readily adopted by almost every one.
When the controversy between Lavoisier and the phlogistic chemists was at
its height, the followers of Stahl had taunted Lavoisier with being unable
to explain the production of hydrogen (or phlogiston as they thought)
during the solution of metals in acids; but when Lavoisier learned the
composition of water, he had an answer sufficient to quell these taunts.
The metal, said Lavoisier, decomposes the water which is always present
along with the acid, hydrogen is thus evolved, and the metallic calx or
oxide so produced dissolves in the acid and forms a salt. If this
explanation were correct--and there was an immense mass of evidence in its
favour and apparently none against it--then all the salts produced by the
action of acids on metals necessarily contained oxygen.
The Lavoisierian view of a salt, as a compound of a metallic oxide--or
base--with a non-metallic oxide--or acid--seemed the only explanation which
could be accepted by any reasonable chemist: in the early years of this
century it reigned supreme.
Public-domain text, read in full here on John Shaqi.
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