Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Before further experiments could be made it was necessary that Davy should
form an hypothesis--that he should mentally connect the appearance of the
nitric acid with some other phenomenon sufficient to produce this
appearance; he could then devise experiments which would determine whether
the connection supposed to exist between the two phenomena really did exist
or not.
Now, of the constituents of nitric acid--nitrogen, hydrogen and oxygen--all
except the first named are present in pure water; nitrogen is present in
large quantity in the ordinary atmosphere. It was only necessary to assume
that some of the hydrogen and oxygen produced during the electrolysis of
water seized on and combined with some of the nitrogen in the air which
surrounded that water, and the continual production of nitric acid during
the whole process of electrolysis was explained.
But how was this assumption to be proved or disproved? Davy adopted a
method frequently made use of in scientific investigations:--remove the
assumed cause of a phenomenon; if the phenomenon ceases to be produced, the
assumed cause is probably the real cause. Davy surrounded the little gold
cups containing the water to be electrolysed with a glass jar which he
connected with an air-pump; he exhausted most of the air from the jar and
then passed the electric current through the water. Very little nitric acid
appeared. He now again took out most of the air from the glass jar,
admitted some hydrogen to supply its place, and again pumped this out. This
process he repeated two or three times and then passed the electric
current. _No_ acid appeared in the water. He admitted air into the glass
vessel; nitric acid began to be produced. Thus he proved that whenever air
was present in contact with the water being electrolysed, nitric acid made
its appearance, and when the air was wholly removed the acid ceased to be
produced. As he had previously shown that the production of this acid was
not to be traced to impurities in the water, to the nature of the vessel
used to contain the water, or to the nature of the material of which the
poles of the battery were composed, the conclusion was forced upon him that
the production of nitric acid in the water, and the presence of ordinary
air around the water invariably existed together; that if one of these
conditions was present, the other was also present--in other words, that
one was the cause of the other.
The result of this exhaustive and brilliant piece of work is summed up by
Davy in these words: "It seems evident then that water, chemically pure, is
decomposed by electricity into gaseous matter alone, into oxygen and
hydrogen."
Public-domain text, read in full here on John Shaqi.
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