Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
From the effects of the electric current on glass, Davy argued that other
earthy compounds would probably undergo change under similar conditions. He
therefore had little cups of gypsum made, in which he placed pure water,
and passed an electric current through the liquid. Lime was formed around
the negative, and sulphuric acid around the positive pole. Using similar
apparatus, he proved that the electric current decomposes very many
minerals into an earthy or alkaline base and an acid.
Picturing to himself the little particles of a salt as being split by the
electric current each into two smaller particles, one possessed of acid and
the other of alkaline properties, Davy thought it might be possible to
intercept the progress of these smaller particles, which he saw ever
travelling towards the positive and negative poles of the battery. He
accordingly connected these small glass vessels by threads of washed
asbestos; in one of the outer vessels he placed pure water, in the other an
aqueous solution of sulphate of potash, and in the central vessel he placed
ammonia. The negative pole of the battery being immersed in the sulphate of
potash, and the positive pole in the water, it was necessary for the
particles of sulphuric acid--produced by the decomposition of the sulphate
of potash--to travel through the ammonia in the central vessel before they
could find their way to the positive pole. Now, ammonia and sulphuric acid
cannot exist in contact--they instantly combine to form sulphate of
ammonia; the sulphuric acid particles ought therefore to be arrested by the
ammonia. But the sulphuric acid made its appearance at the positive pole
just as if the central vessel had contained water. It seemed that the
mutual attraction ordinarily exerted between sulphuric acid and ammonia was
overcome by the action of the electric current. Ammonia would generally
present an insuperable barrier to the progress of sulphuric acid, but the
electrical energy appeared to force the acid particles over this barrier;
they passed towards their goal as if nothing stood in their way.
Experiments are now multiplied by Davy, and the general conclusion drawn is
that "Hydrogen, the alkaline substances, the metals and certain metallic
oxides are attracted by negatively electrified metallic surfaces, and
repelled by positively electrified metallic surfaces; and contrariwise,
that oxygen and acid substances are attracted by positively electrified
metallic surfaces, and repelled by negatively electrified metallic
surfaces; and these attractive and repulsive forces are sufficiently
energetic to destroy or suspend the usual operation of chemical
affinity."[10]
Public-domain text, read in full here on John Shaqi.
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