Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Pursuing the train of thought initiated by the experiments which I have
described, Davy entered upon a series of researches which led him to
consider every chemical substance as possessing definite electrical
relations towards every other substance. "As chemical attraction between
two bodies seems to be destroyed by giving one of them an electrical state
different from that which it naturally possessed--that is, by bringing it
into a state similar to the other--so it may be increased by exalting its
natural energy." Thus zinc, a metal easily oxidized, does not combine with
oxygen when negatively electrified, whereas silver, a metal oxidized with
difficulty, readily combines with oxygen when positively electrified.
Substances in opposite electrical states appear to combine chemically, and
the greater the electrical difference the greater the readiness with which
chemical combination is effected. Electrical energy and chemical attraction
or _affinity_ are evidently closely connected; perhaps, said Davy, they are
both results of the same cause.
Thus Davy arrived at the conception of a system of bodies as maintained in
equilibrium by the mutual actions and reactions of both chemical and
electrical forces; by increasing either of these a change is necessarily
produced in the other. Under certain electrical conditions the bodies will
exert no chemical action on one another, but such action may be started by
changing these electrical conditions, or, on the other hand, by changes in
the chemical relations of the bodies a change in the electrical relations
may be induced. Thus Davy found that if plates of copper and sulphur are
heated, the copper exhibits a positive and the sulphur a negative
electrical condition; that these electrical states become more marked as
temperature rises, until the melting point of sulphur is reached, when the
copper and sulphur combine together chemically and produce sulphide of
copper.
Public-domain text, read in full here on John Shaqi.
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