Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
When water is electrolysed, Davy looked on the oppositely electrified
metallic plates in the battery as striving to attain a state of
equilibrium; the negatively electrified zinc strives to gain positive
electricity from the copper, which strives to gain negative electricity
from the zinc. The water he regarded as the carrier of these electricities,
the one in this direction, the other in that. In thus acting as a carrier,
the water is itself chemically decomposed, with production of hydrogen and
oxygen; but this chemical rearrangement of some of the substances which
composed the original system (of battery and water) involves a fresh
disturbance of electrical energy, and so the process proceeds until the
whole of the water is decomposed or the whole of the copper or zinc plate
is dissolved in the battery. If the water were not chemically decomposed,
Davy thought that the zinc and copper in the battery would quickly attain
the state of electrical equilibrium towards which they continually strive,
and that the current would therefore quickly cease.
Davy thought that "however strong the natural electrical energies of the
elements of bodies may be, yet there is every probability of a limit to
their strength; whereas the powers of our artificial instruments seem
capable of indefinite increase." By making use of a very powerful battery,
he hoped to be able to decompose substances generally regarded as simple
bodies.
Taking a wide survey of natural phenomena, he sees these two forces, which
we call chemical and electrical, everywhere at work, and by their mutual
actions upholding the material universe in equilibrium. In the outbreaks
of volcanoes he sees the disturbance of this equilibrium by the undue
preponderance of electrical force; and in the formation of complex minerals
beneath the surface of the earth, he traces the action of those chemical
attractions which are ever ready to bring about the combination of
elements, if they are not held in check by the opposing influence of
electrical energy.
We shall see how the great and philosophical conception of Davy was used by
Berzelius, and how, while undoubtedly gaining in precision, it lost much in
breadth in being made the basis of a rigid system of chemical
classification.
Davy's hope that the new instrument of research placed in the hands of
chemists by Volta would be used in the decomposition of supposed simple
substances was soon to be realized. A year after the lecture "On some
Chemical Agencies of Electricity," Davy was again the reader of the
Bakerian Lecture; this year (1807) it was entitled, "On some New Phenomena
of Chemical Change produced by Electricity, particularly the Decomposition
of the Fixed Alkalis; and the Exhibition of the New Substances which
constitute their Bases; and on the General Nature of Alkaline Bodies."
Public-domain text, read in full here on John Shaqi.
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