Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But the analysis of potash and soda was not sufficient for Davy; he
determined to accomplish the synthesis of these substances. For this
purpose he collected small quantities of the newly discovered metals, by
conducting the electrolysis of potash and soda under experimental
conditions such that the metals, as soon as produced, were plunged under
the surface of naphtha, a liquid which does not contain oxygen, and which
protected them from the action of the surrounding air.
A weighed quantity of each metal was then heated in a stream of pure dry
oxygen, the products were collected and weighed, and it was found that
solutions of these products in water possessed all the properties of
aqueous solutions of potash and soda.
The new metals were now obtained in larger quantity by Davy, and their
properties carefully determined by him; they were named _potassium_ and
_sodium_ respectively. They were shown to possess all those properties
which were generally accepted as characteristic of metal, except that of
being heavy. The new metals were extremely light, lighter than water. For
some time it was difficult to convince all chemists that a metal could be a
very light substance. We are assured that a friend of Davy, who was shown
potassium for the first time, and was asked what kind of substance he
supposed it to be, replied, "It is metallic, to be sure;" "and then,
balancing it on his finger, he added in a tone of confidence, 'Bless me,
how heavy it is!'"
Davy argued that since the alkalis, potash and soda, were found to be
oxygen compounds of metals, the earths would probably also be found to be
metallic oxides. In the year 1808 he succeeded in decomposing the three
earths, lime, baryta and strontia, and in obtaining the metals _calcium_,
_barium_ and _strontium_, but not in a perfectly pure condition, or in any
quantity. He also got evidence of the decomposition of the earths silica,
alumina, zirconia and beryllia, by the action of powerful electric
currents, but he did not succeed in obtaining the supposed metallic bases
of these substances.
So far Davy's discoveries had all tended to confirm the generally accepted
view which regarded alkalis and earths as metallic oxides. But we found
that the outcome of these views was to regard all salts--and among these,
of course, common salt--as oxygen compounds.[11] Acids were oxygen
compounds, bases were oxygen compounds, and as salts were produced by the
union of acids with bases, they, too, must necessarily be oxygen compounds.
Berthollet had thrown doubt on the universality of Lavoisier's name
"oxygen," _the_ acidifier, but he had not conclusively proved the existence
of any acid which did not contain oxygen.
The researches of Davy naturally led him to consider the prevalent views
regarding acids, bases and salts.
Public-domain text, read in full here on John Shaqi.
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