Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Muriatic (or as we now call it hydrochloric) acid had long been a
stumbling-block to the thorough-going Lavoisierian chemists. Oxygen could
not be detected in it, yet it ought to contain oxygen, because oxygen is
the acidifier. Of course, if muriatic acid contains oxygen, the
salts--muriates--produced by the action of this acid on alkalis and earths
must also contain oxygen. Many years before this time the action of
muriatic acid on manganese ore had been studied by the Swedish chemist
Scheele, who had thus obtained a yellow-coloured gas with a very strong
smell. Berthollet had shown that when a solution of this gas in water is
exposed to sunlight, oxygen is evolved and muriatic acid is produced. The
yellow gas was therefore supposed to be, and was called, "oxidized muriatic
acid," and muriatic acid was itself regarded as composed of oxygen and an
unknown substance or _radicle_.
In 1809 Gay-Lussac and Thenard found that one volume of hydrogen united
with one volume of the so-called oxidized muriatic acid to form muriatic
acid; the presence of hydrogen in this acid was therefore proved.
When Davy began (1810-11) to turn his attention specially to the study of
salts, he adopted the generally accepted view that muriatic acid is a
compound of oxygen and an unknown radicle, and that by the addition of
oxygen to this compound oxidized muriatic acid is produced. But unless Davy
could prove the presence of oxygen in muriatic acid he could not long hold
the opinion that oxygen was really a constituent of this substance. He
tried to obtain direct evidence of the presence of oxygen, but failed. He
then set about comparing the action of muriatic acid on metals and metallic
oxides with the action of the so-called oxidized muriatic acid on the same
substances. He showed that salt-like compounds were produced by the action
of oxidized muriatic acid either on metals or on the oxides of these
metals, oxygen being evolved in the latter cases; and that the same
compounds and water were produced by the action of muriatic acid on the
same metallic oxides.
These results were most easily and readily explained by assuming the
so-called oxidized muriatic acid to be an elementary substance, and
muriatic acid to be a compound of this element with hydrogen. To the new
element thus discovered--for he who establishes the elementary nature of a
substance may almost be regarded as its discoverer--Davy gave the name of
_chlorine_, suggested by the yellow colour of the gas (from Greek, =
_yellow_). He at once began to study the analogies of chlorine, to find by
experiment which elements it resembled, and so to classify it. Many metals,
he found, combined readily with chlorine, with evolution of heat and light.
It acted, like oxygen, as a supporter of combustion; it was, like oxygen,
attracted towards the negative pole of the voltaic battery; its compound
with hydrogen was an acid; hence said Davy chlorine, like oxygen, is a
supporter of combustion and also an acidifier.
Public-domain text, read in full here on John Shaqi.
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