Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
We have already seen that silica was regarded by most chemists as a typical
earth; but Berzelius found that in the electrolysis of compounds of silica,
this substance appeared at the positive pole of the battery--that is, the
atom of silica belonged to the negatively electrified order of atoms.
Silica was almost certainly an oxide; but electro-negative oxides are, as a
class, acids; therefore silica was probably an acid. The supposition of
the acid character of silica was amply confirmed by the mineralogical
analyses and experiments of Berzelius. He showed that most of the earthy
minerals are compounds of silica with electro-positive metallic oxides, and
that silica plays the part of an acid in these minerals; and in 1823 he
obtained the element silicon, the oxide of which is silica. On this basis
Berzelius reared a system of classification in mineralogy which much aided
the advance of that branch of natural science.
By the work of Berzelius and Davy the Lavoisierian conception of acid has
now been much modified and extended; it has been rendered less rigid, and
is therefore more likely than before to be a guide to fresh discoveries.
The older view of acid and alkali was based, for the most part, on a
qualitative study of the reactions of chemical substances: bodies were
placed in the same class because they were all sour, or all turned
vegetable blues to red, etc. This was followed by a closer study of the
composition of substances, and by attempts to connect the properties of
these substances with their composition; but when this attempt resulted in
the promulgation of the dictum that "oxygen is the acidifying principle,"
it began to be perceived that a larger basis of fact must be laid before
just conclusions could be drawn as to the connections between properties
and composition of substances. This larger basis was laid by the two
chemists whose work we have now reviewed. Of the life of one of these men
I have already given such a sketch as I can from the materials available to
me; of the life of the other we happily possess ample knowledge. Let us now
consider the main features of this life.
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Public-domain text, read in full here on John Shaqi.
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