Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Now, if two elementary atoms unite, the compound atom must--according to
the Berzelian views--be characterized either by positive or negative
electricity. This compound atom, if positive, will exhibit affinity for
other compound atoms in which negative electricity predominates; if
negative, it will exhibit affinity for other positively electrified
compound atoms. If two compound atoms unite chemically, the complex atom so
produced will, again, be characterized by one or other of the two
electricities, and as it is positive or negative, so will it exhibit
affinity for positively or negatively electrified complex atoms. Thus
Berzelius and his followers regarded every compound atom, however complex,
as essentially built up of two parts, one of which was positively and the
other negatively electrified, and which were held together chemically by
virtue of the mutual attractions of these electricities; they regarded
every compound atom as a _dual_ structure. The classification adopted by
Berzelius was essentially a dualistic classification. His system has always
been known in chemistry as _dualism_.
Berzelius divided compound atoms (we should now say molecules) into three
groups or orders--
_Compound atoms of the first order_, formed by the immediate combination of
atoms of two, or in organic compounds of three, elementary substances.
_Compound atoms of the second order_, formed by the combination of atoms of
an element with atoms of the first order, or by the combination of two or
more atoms of the first order.
_Compound atoms of the third order_, formed by combination of two or more
atoms of the second order.
When an atom of the third order was decomposed by an electric current, it
split up, according to the Berzelian teaching, into atoms of the second
order--some positively, others negatively electrified. When an atom of the
second order was submitted to electrolysis, it decomposed into atoms of the
first order--some positively, others negatively electrified.
Berzelius said that a base is an electro-positive oxide, and an acid is an
electro-negative oxide. The more markedly positive an oxide is, the more
basic it is; the more negative it is, the more is it characterized by acid
properties.
One outcome of this teaching regarding acids and bases was to overthrow the
Lavoisierian conception of oxygen as the acidifying element. Some oxides
are positive, others negative, said Berzelius; but acids are characterized
by negative electricity, therefore the presence of oxygen in a compound
does not always confer on that compound acid properties.
Public-domain text, read in full here on John Shaqi.
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