Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Graham's _tube atmolyser_ consisted of a long tobacco-pipe stem placed
inside a rather shorter and considerably wider tube of glass; the pipe stem
was fixed by passing through two corks, one at each end of the glass tube;
through one of these corks there also passed a short piece of glass tubing.
When the instrument was employed, the piece of short glass tubing was
connected with an air-pump, and one end of the pipe stem with the gaseous
mixture--say ordinary air. The air-pump being set in motion, the gaseous
mixture was allowed to flow slowly through the pipe stem; the lighter
ingredient of the mixture passed outwards through the pipe stem into the
wide glass tube more rapidly than the heavier ingredient, and was swept
away to the air-pump; the heavier ingredient could be collected, mixed with
only a small quantity of the lighter, at the other end of the pipe stem. As
Graham most graphically expressed it, "The stream of gas diminishes as it
proceeds, like a river flowing over a pervious bed."
Graham then contrived a very simple experiment whereby he was able to
measure the rate of motion of the molecules of carbonic acid. He introduced
a little carbonic acid into the lower part of a tall cylindrical jar, and
at the close of certain fixed periods of time he determined the amount of
carbonic acid which had diffused upwards through the air into the uppermost
layer of the jar. Knowing the height of the jar, he now knew the distance
through which a small portion of carbonic acid passed in a stated time,
and regarding this small portion as consisting of a great many molecules,
all moving at about equal rates, he had determined the average velocity of
the molecules of carbonic acid. A similar experiment was performed with
hydrogen. The general results were that the molecules of carbonic acid move
about in still air with a velocity equal to seventy-three millimetres per
minute, and that under the same conditions the molecules of hydrogen move
with a velocity equal to about one-third of a metre per minute.[12]
Public-domain text, read in full here on John Shaqi.
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