Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Liebig left Paris in 1824. By the year 1830 he had perfected and applied
that method for the analysis of organic compounds which is now in constant
use wherever organic chemistry is studied; by the same year Dumas had given
the first warning of the attack which he was about to make on the great
structure of dualism raised by Berzelius. In a paper, "On Some Points of
the Atomic Theory," published in 1826, Dumas adopted the distinction made
by Avogadro between molecules and atoms, or between the small particles of
substances which remain undivided during physical actions, and the
particles, smaller than these, which are undivided during chemical actions.
But, unfortunately, Dumas did not mark these two conceptions by names
sufficiently definite to enable the readers of his memoir to bear the
distinction clearly in mind. The terms "atom" and "molecule" were not
introduced into chemistry with the precise meanings now attached to them
until some time after 1826.
Although the idea of two orders of small particles underlies all the
experimental work described by Dumas in this paper, yet the numbers which
he obtained as representing the actual atomic weights of several
elements--_e.g._ phosphorus, arsenic, tin, silicon--show that he had not
himself carried out Avogadro's hypothesis to its legitimate conclusions.
Two years after this Dumas employed the reaction wherein two volumes of
gaseous hydrochloric acid are produced by the union of one volume of
hydrogen with one volume of chlorine, as an argument which obliged him to
conclude that, if Avogadro's physical hypothesis be accepted, the molecules
of hydrogen and chlorine split, each into two parts, when these gases
combine chemically. But Dumas did not at this time conclude that the
molecular weight of hydrogen must be taken as twice its atomic weight, and
that--hydrogen being the standard substance--the molecular weights of all
gases must be represented by the specific gravities of these gases,
referred to hydrogen as 2.
I have already shortly discussed the method for finding the relative
weights of elementary atoms which is founded on Avogadro's hypothesis,
and, I think, have shown that this hypothesis leads to the definition of
"atom" as the smallest amount of an element in one molecule of any compound
of that element (see p. 142).
This deduction from Avogadro's law is now a part and parcel of our general
chemical knowledge. We wonder why it was not made by Dumas; but we must
remember that a great mass of facts has been accumulated since 1826, and
that this definition of "atom" has been gradually forced on chemists by the
cumulative evidence of those facts.
One thing Dumas did do, for which the thanks of every chemist ought to be
given him; he saw the need of a convenient method for determining the
densities of compounds in the gaseous state, and he supplied this need by
that simple, elegant and trustworthy method, still in constant use, known
as _Dumas's vapour density process_.
Public-domain text, read in full here on John Shaqi.
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