Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
While Dumas was working out the details of this analytical method, which
was destined to be so powerful an instrument of research, Liebig was
engaged in similar work; he was perfecting that process for the analysis of
organic compounds which has since played so important a part in the
advancement of this branch of chemical science. The processes in use during
the first quarter of this century for determining the amounts of carbon,
hydrogen, and oxygen in compounds of those elements, were difficult to
conduct and gave untrustworthy results. Liebig adopted the principle of
the method used by Lavoisier, viz. that the carbon in a compound can be
oxidized, or burnt, to carbonic acid, and the hydrogen to water. He
contrived a very simple apparatus wherein this burning might be effected
and the products of the burning--carbonic acid and water--might be arrested
and weighed. Liebig's apparatus remains now essentially as it was presented
to the chemical world in 1830. Various improvements in details have been
made; the introduction of gas in place of charcoal as a laboratory fuel has
given the chemist a great command over the process of combustion, but in
every part of the apparatus to-day made use of in the laboratory is to be
traced the impress of the master's hand. A weighed quantity of the
substance to be analyzed is heated with oxide of copper in a tube of hard
glass; the carbon is burnt to carbonic acid and the hydrogen to water at
the expense of the oxygen of the copper oxide. Attached to the combustion
tube is a weighed tube containing chloride of calcium, a substance which
greedily combines with water, and this tube is succeeded by a set of three
or more small bulbs, blown in one piece of glass, and containing an aqueous
solution of caustic potash, a substance with which carbonic acid readily
enters into combination. The chloride of calcium tube and the potash bulbs
are weighed before and after the experiment; the increase in weight of the
former represents the amount of water, and the increase in weight of the
latter the amount of carbonic acid obtained by burning a given weight of
the compound under examination. As the composition of carbonic acid and of
water is known, the amounts of carbon and of hydrogen in one hundred parts
of the compound are easily found; the difference between the sum of these
and one hundred represents the amount of oxygen in one hundred parts of the
compound. If the compound should contain elements other than these three,
those other elements are determined by special processes, the oxygen being
always found by difference.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account