Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
From this time the progress of organic chemistry became rapid. Dumas
continued the researches upon ethers which he had commenced at Geneva, and
by the year 1829 or so he had established the relations which exist between
ethers and alcohols on the one hand, and ethers and acids on the other.
This research, a description of the details of which I cannot introduce
here as it would involve the use of many technical terms and assume the
possession by the reader of much technical knowledge, was followed by
others, whereby Dumas established the existence of a series of compounds
all possessed of the chemical properties of alcohol, all containing carbon,
hydrogen and oxygen, but differing from one another by a constant amount of
carbon and hydrogen. This discovery of a series of alcohols, distinguished
by the possession of certain definite properties whereby they were marked
off from all other so-called organic compounds, was as the appearance of a
landmark to the traveller in a country where he is without a guide. The
introduction of the comparative method of study into organic chemistry--the
method, that is, which bases classification on a comparison of large groups
of compounds, and which seeks to gather together those substances which are
like and to separate those which are unlike--soon began to bear fruit. This
method suggested to the experimenter new points of view from which to
regard groups of bodies; analogies which were hidden when a few substances
only were considered, became prominent as the range of view was widened.
What the gentle Elia calls "fragments and scattered pieces of truth,"
"hints and glimpses, germs, and crude essays at a system," became
important. There was work to be done, not only by the master spirits who,
looking at things from a central position of vantage, saw the relative
importance of the various detailed facts, but also by those who could only
"beat up a little game peradventure, and leave it to knottier heads, more
robust constitutions, to run it down."
Twenty years before the time of which we are now speaking Davy had
decomposed the alkalis potash and soda; as he found these substances to be
metallic oxides, he thought it very probable that the other well-known
alkali, ammonia, would also turn out to be the oxide of a metal. By the
electrolysis of salts formed by the action of ammonia on acids, using
mercury as one of the poles of the battery, Davy obtained a strange-looking
spongy substance which he was inclined to regard as an alloy of the
metallic base of ammonia with mercury. From the results of experiments by
himself and others, Davy adopted a view of this alloy which regarded it as
containing a _compound radicle_, or group of elementary atoms which in
certain definite chemical changes behaved like a single elementary atom.
To this compound radicle he gave the name of _ammonium_.
Public-domain text, read in full here on John Shaqi.
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