Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
As an aqueous solution of potash or soda was regarded as a compound of
water and oxide of potassium or sodium, so an aqueous solution of ammonia
was regarded as a compound of water and oxide of ammonium.
When the composition of this substance, ammonium, came to be more
accurately determined, it was found that it might be best represented as a
compound atom built up of one atom of nitrogen and four atoms of hydrogen.
The observed properties of many compounds obtained from ammonia, and the
analogies observed between these and similar compounds obtained from potash
and soda, could be explained by assuming in the compound atom (or better,
in the molecule) of the ammonia salt, the existence of this group of atoms,
acting as one atom, called ammonium.
The reader will not fail to observe how essentially atomic is this
conception of compound radicle. The ultimate particle, the molecule, of a
compound has now come to be regarded as a structure built up of parts
called atoms, just as a house is a structure built up of parts called
stones and bricks, mortar and wood, etc. But there may be a closer
relationship between some of the atoms in this molecule than between the
other atoms. It may be possible to remove a group of atoms, and put another
group--or perhaps another single atom--in the place of the group removed,
without causing the whole atomic structure to fall to pieces; just as it
may be possible to remove some of the bricks from the wall of a house, or a
large wooden beam from beneath the lintels, and replace these by other
bricks or by a single stone, or replace the large wooden beam by a smaller
iron one, without involving the downfall of the entire house. The group of
atoms thus removable--the compound radicle--may exist in a series of
compounds. As we have an oxide, a sulphide, a chloride, a nitrate, etc.,
of sodium, so we may have an oxide, a sulphide, a chloride, a nitrate,
etc., of ammonium. The compounds of sodium are possessed of many properties
in common; this is partly explained by saying that they all contain one or
more atoms of the element sodium. The compounds of ammonium possess many
properties in common, and this is partly explained if we assume that they
all contain one or more atoms of the compound radicle ammonium.
Public-domain text, read in full here on John Shaqi.
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