Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
The visitors at one of the royal _soirees_ at the Tuileries were much
annoyed by the irritating vapours which came from the wax candles used to
illuminate the apartments; Dumas was asked to examine the candles and find
the reason of their peculiar behaviour. He found that the manufacturer had
used chlorine to bleach the wax, that some of this chlorine remained in the
candles, and that the irritating vapours which had annoyed the guests of
Charles X. contained hydrochloric acid, produced by the union of chlorine
with part of the hydrogen of the wax. Candles bleached by some other means
than chlorine were in future used in the royal palaces; and the unitary
theory, which was to overthrow the dualism of Berzelius, began to arise in
the mind of Dumas.
The retention of a large quantity of chlorine by wax could scarcely be
explained by assuming that the chlorine was present only as a mechanically
held impurity. Dumas thoroughly investigated the action of chlorine on wax
and other organic compounds; and in 1834 he announced that hydrogen in
organic compounds can be exchanged for chlorine, every volume of hydrogen
given up by the original compound being replaced by an equal volume of
chlorine.
Liebig and Woehler made use of a similar conception to explain the results
which they had obtained about this time in their study of the oil of bitter
almonds, a study which will be referred to immediately.
The progress of this bold innovation made by Dumas was much advanced by the
experiments and reasonings of two French chemists, whose names ought
always to be reverenced by students of chemistry as the names of a pair of
brilliant naturalists to whom modern chemistry owes much. _Gerhardt_ was
distinguished by clearness of vision and expression; _Laurent_ by
originality, breadth of mind and power of speculation.
Laurent appears to have been the first who made a clear statement of the
fundamental conception of the unitary theory: "Many organic compounds, when
treated with chlorine lose a certain number of equivalents of hydrogen,
which passes off as hydrochloric acid. An equal number of equivalents of
chlorine takes the place of the hydrogen so eliminated; thus the physical
and chemical properties of the original substance are not profoundly
changed. The chlorine occupies the place left vacant by the hydrogen; the
chlorine plays in the new compound the same part as was played by the
hydrogen in the original compound."
The replacement of electro-positive hydrogen by electro-negative chlorine
was against every canon of the dualistic chemistry; and to say that the
physical and chemical properties of the original compound were not
profoundly modified by this replacement, seemed to be to call in question
the validity of the whole structure raised by the labours during a quarter
of a century of one universally admitted to be among the foremost chemists
of his age.
Public-domain text, read in full here on John Shaqi.
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