Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But facts accumulated. By the action of chlorine on alcohol Liebig
obtained _chloroform_ and _chloral_, substances which have since been so
largely applied to the alleviation of human suffering; but it was Dumas who
correctly determined the composition of these two compounds, and showed how
they are related to alcohol and to one another.
Liebig's reception of the corrections made by Dumas in his work furnishes a
striking example of the true scientific spirit. "As an excellent
illustration," said Liebig, "of the mode in which errors should be
corrected, the investigation of chloral by Dumas may fitly be introduced.
It carried conviction to myself, as I think to everybody else, not by the
copious number of analytical data opposed to the not less numerous results
which I had published, but because these data gave a simpler explanation
both of the formation and of the changes of the substances in question."
One of the most important contributions to the new views was made by Dumas
in his paper on the action of chlorine on acetic acid (1833), wherein he
proved that the product of this action, viz. _trichloracetic acid_, is
related to the parent substance by containing three atoms of chlorine in
place of three atoms of hydrogen in the molecule; that the new substance
is, like the parent substance, a monobasic acid; that its salts are very
analogous in properties to the salts of acetic acid; that the action of the
same reagents on the two substances is similar; and finally, that the
existence of many derivatives of these compounds could be foretold by the
help of the new hypothesis, which derivatives ought not to exist according
to the dualistic theory, but which, unfortunately for that theory, were
prepared and analyzed by Dumas.
Public-domain text, read in full here on John Shaqi.
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