Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
For a time it seemed also as if the new chemistry could do without the
compound radicle which had been so much used by Berzelius; but the pressure
of facts soon drove the unitary chemists to recognize the value of that
hypothesis which looked on parts of the molecule as sometimes more closely
associated than other parts--which recognized the existence of atomic
structures within the larger molecular structures. As a house is not simply
a putting together of so many bricks, so much mortar, so many doors and
windows, so many leaden pipes, etc., but rather a definite structure
composed of parts, many of which are themselves also definite structures,
such as the window and its accessory parts, the door with its lintel and
handle, etc., so to the unitary chemists did the molecule appear to be
built up of parts, some of which, themselves composed of yet smaller parts,
discharged a particular function in the molecular economy.
A general division of a plant might describe it as a structure consisting
of a stem, a root, and leaves. Each of the parts, directly by its
individual action and indirectly by the mutual action between it and all
the other parts, contributes to the growth of the whole plant; but if the
stem, or root, or leaves be further analyzed, each is found to consist of
many parts, of fibres and cells and tissue, etc. We may liken the plant to
the molecule of an organic compound; the root, the stem and the leaves to
the compound radicles of which this molecule is built up, and the tissue,
fibres, etc., to the elementary atoms which compose these compound
radicles. The molecule is one whole, possessed of definite structure and
performing a definite function by virtue of the nature and the arrangement
of its parts.
Many years elapsed after the publication of the researches of Dumas, and of
Liebig and Woehler, before such a conception of the molecule as this was
widely accepted by chemists. The opposition of the older school, headed by
their doughty champion Berzelius, had to be overcome; the infallibility of
some of the younger members of the new school had to be checked; facts had
to be accumulated, difficulties explained, weak analogies abandoned and
strong ones rendered stronger by research; special views of the structure
of this or that molecule, deduced from a single investigation, had to be
supplemented and modified by wider views gained by the researches of many
workers. It was not till 1867 that Liebig, when asked by Dumas at a dinner
given during the French Exhibition to the foreign chemists, why he had
abandoned organic chemistry, replied that "now, with the theory of
substitution as a foundation, the edifice may be built up by workmen:
masters are no longer needed."
Laurent and Gerhardt did noble work in advancing the unitary theory; to
them is largely due the fruitful conception of types, an outcome of Dumas's
work, which owed its origin to the flickering of the wax candles in the
Tuileries during the royal _soiree_.
Public-domain text, read in full here on John Shaqi.
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