Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Chlorine can be substituted for hydrogen in acetic acid, and the product is
closely related in its properties to the parent substance; various atoms or
groups of atoms can be substituted by other groups in the derivatives of
oil of bitter almonds, but a close analogy in properties runs through all
these compounds: these facts might be more shortly expressed by saying that
acetic and trichloracetic acids belong to the same _type_, and that the
derivatives of bitter-almond oil likewise belong to one _type_.
Laurent carried this conception into inorganic chemistry. Water and potash
did not seem to have much in common, but Laurent said potash is not a
compound of oxide of potassium and water, it is rather a derivative of
water. The molecule of potash is derived from that of water by replacing
one atom of hydrogen in the latter by one atom of potassium; water and
potash belong to the same type.
Thus there was constituted _the water type_.
Light was at once thrown on many facts in organic chemistry. The analogies
between alcohol and water, some of which were first pointed out by Graham
(see p. 235), seemed to follow as a necessary consequence when the molecule
of alcohol was regarded as built on the water type. In place of two atoms
of hydrogen combined with one of oxygen, there was in the alcohol molecule
one atom of the compound radicle _ethyl_ (itself composed of carbon and
hydrogen), one atom of oxygen and one of hydrogen. Alcohol was water with
one hydrogen atom substituted by one ethyl atom; the hydrogen atom was the
atom of what we call an element, the ethyl was the atom of what we call a
compound radicle.
Gerhardt sought to refer all organic compounds to one or other of three
types--the water type, the hydrochloric acid type, and the ammonia type. As
new compounds were prepared and examined, other types had to be introduced.
To follow the history of this conception would lead us into too many
details; suffice it to say that the theory of types was gradually merged in
the wider theory of equivalency, about which I shall have a little to say
in the next chapter.
Public-domain text, read in full here on John Shaqi.
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