Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Dumas's experiments were summed up in the statement that the atom of carbon
is twelve times heavier than the atom of hydrogen. The experimental methods
and the calculations used in this determination involved a knowledge of the
atomic weight of oxygen; in order accurately to determine the value to be
assigned to this constant, Dumas, in conjunction with Boussingault,
undertook a series of experiments on the synthesis of water, which forms
one of the classical researches of chemistry, and wherein the number 16 was
established as representing the atomic weight of oxygen. Stas, from
experiments conducted at a later time with the utmost care and under
conditions eminently fitted to gain accurate results, obtained the number
15.96, in place of 16, for the atomic weight of oxygen; but in a paper
recently published by the veteran Dumas, a source of error is pointed out
which Stas had overlooked in his experiments, and it is shown that this
error would tend slightly to increase the number obtained by Stas.
As the values assigned to the atomic weights of the elements are the very
fundamental data of chemistry, and as we are every day more clearly
perceiving that the mutual relations between the properties of elements and
compounds are closely connected with the relative weights of the elementary
atoms, we can scarcely lay too much stress on such work as this done by
Dumas and Stas. Not many years after the publication of Dalton's "New
System," the hypothesis was suggested by Prout that the atomic weights of
all the elements are represented by whole numbers--that of hydrogen being
taken as unity--that the atom of each element is probably formed by the
putting together of two, three, four, or more atoms of hydrogen, and that
consequently there exists but a single elementary form of matter. Among the
upholders of this hypothesis Dumas has held an important place. He modified
the original statement of Prout, and suggested that all atomic weights are
whole multiples of half of that of hydrogen (that is, are whole multiples
of 1/2). The experiments of Stas seemed to negative this view, but later
work--more especially the important critical revision of the results
obtained by all the most trustworthy workers, conducted by Professor Clarke
of Cincinnati, and published by the Smithsonian Institution as part of
their series of "Constants of Nature"--has shown that we are in no wise
warranted by facts in rejecting Prout's hypothesis as modified by Dumas,
but that the balance of evidence is at present rather in its favour.
Public-domain text, read in full here on John Shaqi.
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