Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
He then strongly heated a weighed quantity of mild magnesia in a retort
connected with a receiver; a few drops of water were obtained in the
receiver, but the magnesia lost six or seven times as much weight as the
weight of the water produced. Black then recalls the experiments of Hales,
wherein airs other than common air had been prepared, and concludes that
the loss of weight noticed when mild magnesia is calcined is probably due
to expulsion, by the heat, of some kind of air. Dissolving some of his mild
magnesia in acid he noticed that effervescence occurred, and from this he
concluded that the same air which, according to his hypothesis, is expelled
by heat, is also driven out from the mild magnesia by the action of acid.
He then proceeded to test this hypothesis. One hundred and twenty grains of
mild magnesia were strongly calcined; the calcined matter, amounting to
seventy grains, was dissolved in dilute oil of vitriol, and this solution
was mixed with common fixed alkali (potassium carbonate). The solid which
was thus produced was collected, washed and weighed; it amounted to a
trifle less than one hundred and twenty grains, and possessed all the
properties--detailed by Black--of the original mild magnesia. But this is
exactly the result which ought to have occurred according to his
hypothesis.
The next step in the investigation was to collect the peculiar air which
Black had proved to be evolved during the calcination of mild magnesia. To
this substance he gave the name of "fixed air," because it was fixed or
held by magnesia. Black established the existence of this air in the
expired breath of animals, and also showed that it was present in the air
evolved during vinous fermentation. He demonstrated several of its
properties; among these, the fact that animals die when placed in this air.
An air with similar properties was obtained by calcining chalk. Black held
that the chemical changes which occur when chalk is calcined are exactly
analogous to those which he had proved to take place when magnesia is
strongly heated. Chalk ought therefore to lose weight when calcined; the
residue ought to neutralize an acid without evolution of any gas, and the
quantity of acid thus neutralized ought to be the same as would be
neutralized by the uncalcined chalk; lastly, it ought to be possible to
recover the uncalcined chalk by adding a fixed alkali to a solution of the
calcined chalk or quicklime.
The actual results which Black obtained were as follows:--
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