Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
This research by Black is a model of what scientific work ought to be. He
begins with a few observations of some natural phenomenon; these he
supplements by careful experiments, and thus establishes a sure basis of
fact; he then builds on this basis a general hypothesis, which he proceeds
to test by deducing from it certain necessary conclusions, and proving, or
disproving, these by an appeal to Nature. This is the scientific method; it
is common sense made accurate.
Very shortly after the publication of the thesis on magnesia and quicklime,
a vacancy occurred in the chemical chair in Glasgow University, and Black
was appointed Professor of Anatomy and Lecturer on Chemistry. As he did not
feel fully qualified to lecture on anatomy, he made an arrangement to
exchange subjects with the Professor of Medicine, and from this time he
delivered lectures on chemistry and on "The Institutes of Medicine."
Black devoted a great deal of care and time to the teaching duties of his
chair. His chemical experimental researches were not much advanced after
this time; but he delivered courses of lectures in which new light was
thrown on the whole range of chemical science.
In the years between 1759 and 1763 Black examined the phenomena of heat and
cold, and gave an explanation, founded on accurate experiments, of the
thermal changes which accompany the melting of solids and the vaporization
of liquids.
If pieces of wood, lead and ice be taken by the hand from a box in which
they have been kept cold, the wood feels cold to the touch, the lead feels
colder than the wood, and the ice feels colder than the lead; hence it was
concluded that the hand receives cold from the wood, more cold from the
lead, and most cold from the ice.
Black however showed that the wood really takes away heat from the hand,
but that as the wood soon gets warmed, the process stops before long; that
the lead, not being so quickly warmed as the wood, takes away more heat
from the hand than the wood does, and that the ice takes away more heat
than either wood or lead.
Black thought that the heat which is taken by melting ice from a warm body
remains in the water which is produced; as soon as winter came he proceeded
to test this supposition by comparing the times required to melt one pound
of ice and to raise the temperature of one pound of water through one
degree, the source of heat being the same in each case. He also compared
the time required to lower the temperature of one pound of water through
one degree with that required to freeze one pound of ice-cold water. He
found that in order to melt one pound of ice without raising its
temperature, as much heat had to be added to the ice as sufficed to raise
the temperature of one pound of water through about 140 degrees of
Fahrenheit's thermometer. But this heat which has been added to the ice to
convert it into water is not indicated by the thermometer. Black called
this "_latent heat_."
Public-domain text, read in full here on John Shaqi.
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