Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
He seemed, therefore, to have a large experimental basis for his answer to
the question, "What happens when a substance burns?" But at a later time it
was proved that iron was also produced by heating the calx of iron with
carbon. The antiphlogistic chemists regarded fixed air as composed of
carbon and dephlogisticated air; the phlogisteans said it was a substance
highly charged with phlogiston. The antiphlogistic school said that calx of
iron is composed of iron and dephlogisticated air; the phlogisteans said it
was iron deprived of its phlogiston. Here was surely an opportunity for a
crucial experiment: when calx of iron is heated with carbon, and iron is
produced, there must either be a production of fixed air (which is a
non-inflammable gas, and forms a white solid substance when brought into
contact with limewater), or there must be an outrush of phlogiston from the
carbon. The experiment was tried: a gas was produced which had no action on
limewater and which was very inflammable; what could this be but
phlogiston, already recognized by this very property of extreme
inflammability? Thus the phlogisteans appeared to triumph. But if we
examine these experiments made by Priestley with the light thrown on them
by subsequent research, we find that they bear the interpretation which he
put on them only because they were not accurate; thus, two gases are
inflammable, but it by no means follows that these gases are one and the
same. We must have more accurate knowledge of the properties of these
gases.
The air around a burning body, such as iron, after a time loses the power
of supporting combustion; but this is merely a qualitative fact. Accurately
to trace the change in the properties of this air, it is absolutely
necessary that exact measurements should be made; when this is done, we
find that the volume of air diminishes during the combustion, that the
burning body gains weight, and that this gain in weight is just equal to
the loss in weight undergone by the air. When the inflammable gas produced
by heating calx of iron with carbon was carefully and _quantitatively_
analyzed, it was found to consist of carbon and oxygen (dephlogisticated
air), but to contain these substances in a proportion different from that
in which they existed in fixed air. It was a new kind of air or gas; it
was _not_ hydrogen.
This account of Priestley's experiments and conclusions regarding
combustion shows how easy it is in natural science to interpret
experimental results, especially when these results are not very accurate,
in accordance with a favourite theory; and it also illustrates one of the
lessons so emphatically taught by all scientific study, viz. the necessity
of suspending one's judgment until accurate measurements have been made,
and the great wisdom of then judging cautiously.
About 1779 Priestley left Lord Shelburne, and went as minister of a chapel
to Birmingham, where he remained until 1791.
Public-domain text, read in full here on John Shaqi.
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