Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Thinking that by measuring the extent to which the _phlogistication_ (we
would now say the _deoxidation_) of common air was carried by mixing
measured quantities of common and inflammable airs and exploding this
mixture, he might be able to determine the amount of phlogiston in a given
volume of inflammable air, he mixed the two airs in glass tubes, through
the sides of which he had cemented two pieces of wire, sealed the tubes,
and exploded the mixture by passing electric sparks from wire to wire. The
residual air now contained, according to Priestley, more phlogiston, and
therefore relatively less dephlogisticated air than before the explosion.
He made various measurements of the quantities of dephlogisticated air in
the tubes, but without getting any constant results. He noticed that after
the explosions the insides of the tubes were covered with moisture. At a
later time he exploded a mixture of dephlogisticated and inflammable airs
(oxygen and hydrogen) in a copper globe, and recorded the fact that after
the explosion the globe contained a little water. Priestley was here
apparently on the eve of a great discovery. "In looking for one thing,"
says Priestley, "I have generally found another, and sometimes a thing of
much more value than that which I was in quest of." Had he performed the
experiment of exploding dephlogisticated and inflammable airs with more
care, and had he made sure that the airs used were quite dry before the
explosion, he would probably have found a thing of indeed much more value
than that of which he was in quest; he would probably have discovered the
compound nature of water--a discovery which was made by Cavendish three or
four years after these experiments described by Priestley.
Some very curious observations were made by Priestley regarding the colour
of the gas obtained by heating "spirit of nitre" (_i.e._ nitric acid). He
showed that a yellow gas or air is obtained by heating colourless liquid
spirit of nitre in a sealed glass tube, and that as the heating is
continued the colour of the gas gets darker, until it is finally very dark
orange red. These experiments have found an explanation only in quite
recent times.
Another discovery made by Priestley while in Birmingham, viz. that an acid
is formed when electric sparks are passed through ordinary air for some
time, led, in the hands of Cavendish--an experimenter who was as careful
and deliberate as Priestley was rapid and careless--to the demonstration of
the composition of nitric acid.
Public-domain text, read in full here on John Shaqi.
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