Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But before considering the work of Lavoisier, I should like to point out
that many of the physical characters of common air had been clearly
established in the later years of the seventeenth century by the Honourable
Robert Boyle. In the "Sceptical Chymist," published in 1661, Mr. Boyle had
established the fact that air is a material substance possessed of weight,
that this air presses on the surface of all things, and that by removing
part of the air in an enclosed space the pressure within that space is
diminished. He had demonstrated that the boiling point of water is
dependent on the pressure of the air on the surface of the water. Having
boiled some water "a pretty while, that by the heat it might be freed from
the latitant air," he placed the vessel containing the hot water within the
receiver of an arrangement which he had invented for sucking air out of an
enclosed space; as soon as he began to suck out air from this receiver, the
water boiled "as if it had stood over a very quick fire.... Once, when the
air had been drawn out, the liquor did, upon a single exsuction, boil so
long with prodigiously vast bubbles, that the effervescence lasted almost
as long as was requisite for the rehearsing of a _Pater noster_." Boyle had
gone further than the qualitative fact that the volume of an enclosed
quantity of air alters with changes in the pressure to which that air is
subjected; he had shown by simple and accurate experiments that "the volume
varies inversely as the pressure." He had established the generalization of
so much importance in physical science now known as _Boyle's law_.
The work of the Honourable Henry Cavendish will be considered in some
detail in the book on "The Physicists" belonging to this series, but I must
here briefly allude to the results of his experiments on air published in
the _Philosophical Transactions_ for 1784 and 1785.
Cavendish held the ordinary view that when a metal burns in air, the air is
thereby phlogisticated; but why is it, he asked, that the volume of air is
decreased by this process? It was very generally said that fixed air was
produced during the calcination of metals, and was absorbed by the calx.
But Cavendish instituted a series of experiments which proved that no fixed
air could be obtained from metallic calces. In 1766 inflammable air
(hydrogen) was discovered by Cavendish; he now proved that when this air is
exploded with dephlogisticated air (oxygen), water is produced. He showed
that when these two airs are mixed in about the proportion of two volumes
of hydrogen to one volume of oxygen, the greater part, if not the whole of
the airs is condensed into water by the action of the electric spark. He
then proceeded to prove by experiments that when common air is exploded
with inflammable air water is likewise produced, and phlogisticated air
(_i.e._ nitrogen) remains.
Public-domain text, read in full here on John Shaqi.
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