Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
The accuracy and thoroughness of Lavoisier's work, and the acuteness of his
reasoning powers, are admirably illustrated in two papers, published in the
Memoirs of the Academy for 1770, on the alleged conversion of water into
earth.
When water is boiled for a long time in a glass vessel a considerable
quantity of white siliceous earth is found in the vessel. This apparent
conversion or transmutation of water into earthy matter was quite in
keeping with the doctrines which had been handed down from the times of the
alchemists; the experiment was generally regarded as conclusively proving
the possibility of changing water into earth. Lavoisier found that after
heating water for a hundred and one days in a closed _and weighed_ glass
vessel, there was no change in the total weight of the vessel and its
contents; when he poured out the water and evaporated it to dryness, he
obtained 20.4 grains of solid earthy matter; but he also found, what had
been before overlooked, that the glass vessel had lost weight. The actual
loss amounted to 17.4 grains. The difference between this and the weight of
the earthy matter in the water, viz. three grains, was set down (and as we
now know justly set down) by Lavoisier to errors of experiment. Lavoisier
therefore concluded that water, when boiled, is not changed into earth, but
that a portion of the earthy matter of which glass is composed is dissolved
by the water. This conclusion was afterwards confirmed by the Swedish
chemist _Scheele_, who proved that the composition of the earthy matter
found in the water is identical with that of some of the constituents of
glass.
By this experiment Lavoisier proved the old alchemical notion of
transmutation to be erroneous; he showed that water is not transmuted into
earth, but that each of these substances is possessed of definite
properties which belong to it and to it only. He established the
all-important generalization--which subsequent research has more amply
confirmed, until it is to-day accepted as the very foundation of every
branch of physical science--that in no process of change is there any
alteration in the total mass of matter taking part in that change. The
glass vessel in which Lavoisier boiled water for so many days lost weight;
but the matter lost by the glass was found dissolved in the water.
Public-domain text, read in full here on John Shaqi.
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