Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Lavoisier contented himself with observing that a metallic calx always
weighed more than the metal from which it was produced; and that as
inflammable air, although much lighter than common air, was distinctly
possessed of weight, it was not possible that a metallic calx could be
metal deprived of inflammable air. He had given a simple explanation of the
process of calcination, and had proved, by accurate experiments, that this
explanation was certainly true in some cases. Although all the known facts
about solution of metals in acids could not as yet be brought within his
explanation, yet none of these facts was absolutely contradictory of that
explanation. He was content to wait for further knowledge. And to gain this
further knowledge he set about devising and performing new experiments. The
upholders of the theory of phlogiston laid considerable stress on the fact
that metals are produced by heating metallic calces in inflammable air; the
air is absorbed, they said, and so the metal is reproduced. It was
obviously of the utmost importance that Lavoisier should learn more about
this inflammable air, and especially that he should know exactly what
happened when this air was burned. He therefore prepared to burn a large
quantity of inflammable air, arranging the experiment so that he should be
able to collect and examine the product of this burning, whatever should be
the nature of that product. But at this time the news was brought to Paris
that Cavendish had obtained water by burning mixtures of inflammable and
dephlogisticated airs. This must have been a most exciting announcement to
Lavoisier; he saw how much depended on the accuracy of this statement, and
as a true student of Nature, he at once set about to prove or disprove it.
On the 24th of June 1783, in the presence of the King and several
notabilities (including Sir Charles Blagden, Secretary of the Royal
Society, who had told Lavoisier of the experiments of Cavendish), Lavoisier
and Laplace burned inflammable and dephlogisticated airs, and obtained
water. As the result of these experiments they determined that one volume
of dephlogisticated air combines with 1.91 volumes of inflammable air to
form water.
A little later Lavoisier completed the proof of the composition of water by
showing that when steam is passed through a tube containing iron filings
kept red hot, inflammable air is evolved and calx of iron remains in the
tube.
Lavoisier could now explain the conversion of a metallic calx into metal by
the action of inflammable air; this air decomposes the calx--that is, the
metallic oxide--combines with its oxygen to form water, and so the metal is
produced.
When a metal is dissolved in diluted vitriolic or muriatic acid a calx is
formed, because, according to Lavoisier, the water present is decomposed by
the metal, inflammable air is evolved, and the dephlogisticated air of the
water combines with the metal forming a calx, which then dissolves in the
acid.
Public-domain text, read in full here on John Shaqi.
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