Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Thus, about the year 1784-85, the theory of phlogiston appeared to be quite
overthrown. The arguments of its upholders, after this time, were not
founded on facts; they consisted of fanciful interpretations of crudely
performed experiments. Cavendish was the only opponent to be dreaded by the
supporters of the new chemistry. But we have seen that although Cavendish
retained the language of the phlogistic theory (see pp. 78, 79) as in his
opinion equally applicable to the facts of combustion with that of the new
or Lavoisierian theory, he nevertheless practically admitted the essential
point of the latter, viz. that calces are compounds of metal and oxygen (or
dephlogisticated air). Although Cavendish was the first to show that water
is produced when the two gases hydrogen and oxygen are exploded together,
it would yet appear that he did not fully grasp the fact that water is a
compound of these two gases; it was left to Lavoisier to give a clear
statement of this all-important fact, and thus to remove the last prop from
under the now tottering, but once stately edifice built by Stahl and his
successors.
The explanation given by Lavoisier of combustion was to a great extent
based on a conception of element and compound very different from that of
the older chemists. In the "Sceptical Chymist" (1661) Boyle had argued
strongly against the doctrine of the four "elementary principles," earth,
air, fire and water, as held by the "vulgar chymists." The existence of
these principles, or some of them, in every compound substance was firmly
held by most chemists in Boyle's time. They argued thus: when a piece of
green wood bums, the existence in the wood of the principle of fire is made
evident by the flame, of the principle of air by the smoke which ascends,
of that of water by the hissing and boiling sound, and of the principle of
earth by the ashes which remain when the burning is finished.[6]
Boyle combated the inference that because a flame is visible round the
burning wood, and a light air or smoke ascends from it, _therefore_ these
principles were contained in the wood before combustion began. He tried to
prove by experiments that one substance may be obtained from another in
which the first substance did not already exist; thus, he heated water for
a year in a closed glass vessel, and obtained solid particles heavier than,
and as he supposed formed from, the water. We have already learned the
true interpretation of this experiment from the work of Lavoisier. Boyle
grew various vegetables in water only, and thought that he had thus changed
water into solid vegetable matter. He tells travellers' tales of the growth
of pieces of iron and other metals in the earth or while kept in
underground cellars.
Public-domain text, read in full here on John Shaqi.
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