Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
In his paper on the properties of the gases constituting the atmosphere,
read to the Manchester Society on November 12, 1802, he stated that one
hundred measures of common air would combine with thirty-six measures of
"nitrous gas" in a narrow tube to produce an oxide of nitrogen, but with
seventy-two measures of the same gas in a wide vessel to produce another
oxide of nitrogen. These facts, he says, "clearly point out the theory of
the process: the elements of oxygen may combine with a certain portion of
nitrous gas, or with twice that portion, but with no intermediate
quantity."
In the concluding paragraph of his paper on absorption of gases by liquids,
read on October 21, 1803, we found (see p. 116) that he had got so far in
his inquiry into the "relative weights of the ultimate particles of bodies"
as to give a table of twenty-one such weights. About this time Dalton made
analyses of two gaseous compounds of carbon--olefiant gas and carburetted
hydrogen or marsh-gas. He found that both are compounds of carbon and
hydrogen; that in one 4.3 parts by weight of carbon are combined with one
part by weight of hydrogen, and in the other the same amount (4.3) of
carbon is combined with two parts by weight of hydrogen.[8]
This was a striking confirmation of his views regarding combination in
multiple proportions, which views followed as a necessary deduction from
the atomic hypothesis. From this time he continued to develop and extend
this hypothesis, and in the year 1808 he published his "New System of
Chemical Philosophy."
The first detailed account of the atomic theory was however given to the
chemical world the year before Dalton's book appeared. During a
conversation with Dalton in the autumn of 1804 Dr. Thomas Thomson learned
the fundamental points of the new theory, and in the third edition of his
"System of Chemistry," published in 1807, he gave an account of Dalton's
views regarding the composition of bodies.
In the same year a paper by Thomson appeared in the _Philosophical
Transactions_, wherein it was experimentally proved that oxalic acid
combines with strontia to form two distinct compounds, one of which
contains twice as much oxalic acid as the other, the amount of strontia
being the same in both. Analyses of the oxalates of potash, published about
the same time by Wollaston, afforded another illustration of the _law of
multiple proportions_, and drew the attention of chemists to Dalton's
theory. But the new theory was opposed by several very eminent chemists,
notably by Sir Humphry Davy. In the autumn of 1807 Wollaston, Thomson and
Davy were present at the dinner of the Royal Society Club, at the Crown
and Anchor, in the Strand. After dinner, these three chemists discussed
the new theory for an hour and a half, Wollaston and Thomson trying to
convince Davy of the truth of Dalton's theory; but "so far from being
convinced, he went away, if possible, more prejudiced against it than
ever."
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account