Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Soon after this Wollaston succeeded in convincing Mr. Davis Gilbert
(afterwards President of the Royal Society) of the justness of the atomic
theory, and he in turn so placed the facts and the reasoning before Davy,
that from this time he became a supporter of the new theory.
In order that the atomic theory should be fruitful of results, it was now
necessary that the values of the atomic weights of many elements should be
carefully determined.
Let us consider what knowledge must be acquired before the value to be
assigned to the atomic weight of an element can be found.
Hydrogen was the element chosen as a standard by Dalton. He assumed that
the atom of hydrogen weighs 1; the atomic weight of any other element is
therefore a number which tells how many times the atom of that element is
heavier than the atom of hydrogen. Thus, when Dalton said the atomic weight
of oxygen is 8, he meant that the atom of oxygen is eight times heavier
than that of hydrogen. How was this number obtained?
Accurate analyses of water show that in this liquid one part by weight of
hydrogen is combined with eight parts by weight of oxygen; but (it is
said) as the atom of hydrogen weighs 1, the atom of oxygen must weigh 8. In
drawing this conclusion it is assumed that the atom, or smallest particle,
of water is built up of one atom of hydrogen and one atom of oxygen. Let it
be assumed that the atom of water contains two atoms of hydrogen and one of
oxygen, then the latter atom must weigh sixteen times as much as each atom
of hydrogen; let it be assumed that three atoms of hydrogen combine with
one atom of oxygen to form an atom of water, then the weight of the oxygen
atom must be twenty-four times that of the hydrogen atom. Any one of these
assumptions will equally satisfy the figures obtained by analyzing water
(1: 8 = 2: 16 = 3: 24). Now, had we any method whereby we could determine
how many times an atom of water is heavier than an atom of hydrogen we
should be able to determine which of the foregoing assumptions is correct,
and therefore to determine the atomic weight of oxygen. Hence, before the
atomic weight of an element can be determined, there must be found some
method for determining the atomic weights of compounds of that element.
Unless this can be done the atomic theory is of little avail in chemistry.
I conceive it to be one of the signal merits of Dalton that he so clearly
lays down rules, the best which could be devised at his time, for
determining the atomic weights of compounds, or, what is the same thing,
for determining the number of elementary atoms in one atom of any
compound. In his "New System" he says that he wishes to show the
importance of ascertaining "the relative weights of the ultimate particles
both of simple and compound bodies, the number of simple elementary
particles which constitute one compound particle, and the number of less
compound particles which enter into the formation of one more compound
particle."
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