Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
Or, even assuming that this _must_ be justified by facts, does it follow
that Dalton's interpretation of the atomic structure of the two oxides of
carbon is necessarily correct? These oxides contain 6 of carbon + 8 of
oxygen, and 6 of carbon + 16 of oxygen, respectively.
Take the second, 6: 16 = 3: 8; assume this to be a binary compound of one
atom of oxygen (weighing 8) with one atom of carbon (weighing 3), then the
other will be a ternary compound containing one atom of oxygen (8) and two
atoms of carbon (6).
Hence it appears that Dalton's rules were too arbitrary, and that they were
insufficient to determine with certainty the atomic weights of some of the
elements. Nevertheless, without some such rules as those of Dalton, no
great advances could have been made in applying the atomic theory to the
facts of chemical combination; and Dalton's rules were undoubtedly founded
on wide considerations. In the appendix to Volume II. of his "New System"
he expressly states that before the number of atoms of two elements present
in the atom of a compound can be determined, it is necessary that many
combinations should be examined, not only of these elements with each
other, but also of each of these with other elements; and he tells us that
to gather together facts bearing on this general question of chemical
synthesis was the object of his work from the time of the promulgation of
the atomic theory.
When we find that Dalton applied the term "atom" to the small particles of
compound bodies, we at once see that by atom he could not always mean "that
which cannot be cut;" he simply meant the smallest particle of a substance
which exhibits the properties of that substance.
A mass of water vapour was conceived by Dalton as "like a mass of small
shot." Each shot exhibited the characteristic chemical properties of water
vapour; it differed from the large quantity of vapour only in mass; but if
one of these little pieces of shot were divided--as Dalton, of course, knew
it could be divided--smaller pieces of matter would be produced. But these
would no longer be water; they would be new kinds of matter. They are
called oxygen and hydrogen.
As aids towards gaining a clear conception of the "atom" of a compound as a
definite building, Dalton made diagrammatic representations of the
hypothetical structures of some of these atoms: the following plate is
copied from the "New System:"--A represents an atom of alum; B, an atom of
nitrate of alumina; C, of barium chloride; D, of barium nitrate; E, of
calcium chloride; F calcium nitrate; G, of calcium sulphate; H, potassium
carbonate; I, of potash; and K, an atom of soda.
[Illustration: Fig. 3.]
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