Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But I think if we consider this application of the term "atom" to elements
and compounds alike, we shall see objections to it. When an atom of a
compound is divided the smaller particles so produced are each very
different in chemical properties from the atom which has just been divided.
We may, if we choose, assume that the atom of an element could in like
manner be divided, and that the products of this division would be
different from the elementary atoms; but such a division of an elementary
atom has not as a matter of fact been yet accomplished, unless we class
among elements substances such as potash and soda, which for many years
were universally regarded as elements, and rightly so regarded because they
had not been decomposed. In Dalton's nomenclature then, the term "atom" is
applied alike to a small particle with definite properties known to be
divisible into smaller particles, each with properties different from those
of the undivided particle, and to a small particle which, so far as our
knowledge goes, cannot be divided into any particle smaller than or
different from itself.
Nevertheless, if the atomic theory was to be victorious, it was necessary
that it should be applied to elements and compounds alike. Until a clear
conception should be obtained, and expressed in accurate language, of the
differences in structure of the ultimate particles of compounds and of
elements, it was perhaps better to apply the term "atom" to both alike.
These two difficulties--(1) the difficulty of attaching to the term "atom"
a precise meaning applicable to elements and compounds alike, and (2) the
difficulty of determining the number of elementary atoms in the atom of a
given compound, and hence of determining the relative weights of elementary
atoms themselves--were for many years stumbling-blocks in the path of the
upholders of the Daltonian theory.
The very great difficulty of clearly comprehending the full meaning of
Dalton's proposed theory becomes apparent when we learn that within three
years from the publication of Part I. of the "New System," facts were made
known by the French chemist Gay-Lussac, and the true interpretation of
these facts was announced by the Italian chemist Avogadro, which facts and
interpretation were sufficient to clear away both the difficulties I have
just mentioned; but that nevertheless it is only within the last ten or
fifteen years that the true meaning of the facts established by Gay-Lussac
and the interpretation given by Avogadro have been generally recognized.
Public-domain text, read in full here on John Shaqi.
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