Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
But we shall better learn the value of some of these discoveries by taking
a general review of the contributions to chemical science of the man who
spent most of his life at work in that room in Stockholm.
The German chemist Richter, in the first or second year of this century,
had drawn attention to the fact that when two neutral compounds, such as
nitrate of potash and chloride of lime, react chemically, the substances
produced by this reaction are also neutral. All the potash combined with
nitric acid in one salt changes places with all the lime combined with
muriatic acid in the other salt; therefore, said Richter, these different
quantities of potash and lime are neutralized by the same quantity of
nitric acid; and, hence, these amounts of potash and lime are chemically
_equivalent_, because these are the amounts which perform the same
reaction, viz. neutralization of a fixed quantity of acid. If then careful
analyses were made of a number of such neutral compounds as those named,
the _equivalents_ of all the commoner "bases" and "acids"[9] might be
calculated.
Richter's own determinations of the equivalents of acids and bases were not
very accurate, but Berzelius was impressed with the importance of this
work. The year before the appearance of Dalton's "New System" (_i.e._ in
1807), he began to prepare and carefully analyze series of neutral salts.
As the work was proceeding he became acquainted with the theory of Dalton,
and at once saw its extreme importance. For some time Berzelius continued
to work on the lines laid down by Dalton, and to accumulate data from which
the atomic weights of elements might be calculated; but he soon
perceived--as the founder of the theory had perceived from the very
outset--that the fundamental conception of each atom of an element as being
a distinct mass of matter weighing more or less than the atom of every
other element, and of each atom of a compound as being built up of the
atoms of the elements which compose that compound,--Berzelius, I say,
perceived that these conceptions must remain fruitless unless means were
found for determining the number of elementary atoms in each compound atom.
We have already learned the rules framed by the founder of the atomic
theory for his guidance in attempting to solve this problem. Berzelius
thought those rules insufficient and arbitrary; he therefore laid down two
general rules, on the lines of which he prosecuted his researches into
chemical synthesis.
"One atom of one element combines with one, two, three, or more atoms of
another element." This is practically the same as Dalton's definitions of
binary, ternary, etc., compounds (p. 132). "Two atoms of one element
combine with three and five atoms of another element." Berzelius here
recognizes the existence of compound atoms of a more complex structure than
any of those recognized by Dalton.
Public-domain text, read in full here on John Shaqi.
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