Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
We shall have to consider in more detail the reasoning whereby Berzelius
arrived at this conception of every compound atom as a _dual_ structure
(see pp. 209-212). At present I wish to notice this conception as lying at
the root of most of the work which he did in extending and applying the
Daltonian theory. I wish to insist on the fact that the atomic theory could
not advance without methods being found for determining the number of
elementary atoms in a compound atom, without clear conceptions being gained
of every compound atom as a structure, and without at least attempts being
made to learn the laws in accordance with which that structure was built.
Before the atomic weight of oxygen could be determined it was necessary
that the number of oxygen and of hydrogen atoms in the atom of water should
be known; otherwise all that could be stated was, the atomic weight of
oxygen is a simple multiple of 8. Berzelius did much to advance chemical
science by the introduction and application of a few simple rules whereby
he determined the number of elementary atoms in various compound atoms. But
as the science advanced, and as more facts came to be known, the Berzelian
rules were found to be too narrow and too arbitrary; chemists sought for
some surer and more generally applicable method than that which Berzelius
had introduced, and the imperious demand for this method at last forced
them to recognize the importance of the great generalization of the Italian
naturalist Avogadro, which they had possessed since the year 1811, but the
meaning of which they had so long failed to understand.
Berzelius made one great step in the direction of recognizing Avogadro's
distinction between atom and molecule when he accepted Gay-Lussac's
generalization that "equal volumes of gases contain equal numbers of
atoms:" but he refused to apply this to other than elementary gases. The
weights of the volumes of elementary gases which combined were, for
Berzelius, also the weights of the atoms of these elements. Thus, let the
weight of one volume of hydrogen be called 1, then two volumes of hydrogen,
weighing 2, combine with one volume of oxygen, weighing 16, to form two
volumes of water vapour; therefore, said Berzelius, the atom of water
consists of two atoms of hydrogen and one atom of oxygen, and the atom of
the latter element is sixteen times heavier than the atom of the former.
Three volumes of hydrogen, weighing 3, combine with one volume of nitrogen,
weighing 14, to form two volumes of ammonia; therefore, said Berzelius, the
atom of ammonia consists of three atoms of hydrogen combined with one atom
of nitrogen, and the nitrogen atom is fourteen times heavier than the atom
of hydrogen.
While Berzelius was applying these rules to the determination of the atomic
weights of the elements, and was conducting the most important series of
analyses known in the annals of the science, two great physico-chemical
discoveries were announced.
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