Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
In the year 1818 the "_law of isomorphism_" was stated by Mitscherlich:
"Compounds the atoms of which contain equal numbers of elementary atoms,
similarly arranged, have the same crystalline form." As thus stated, the
law of isomorphism affirms that if two compounds crystallize in the same
form, the atoms of these compounds are built up of the same number of
elementary atoms--however different may be the nature of the elements in
the compounds--and that these elementary atoms are similarly arranged. This
statement was soon found to be too absolute, and was accordingly modified;
but to go into the history of the law of isomorphism would lead us too far
from the great main path of chemical advance, the course of which we are
seeking to trace.
Berzelius at once accepted Mitscherlich's law, as an aid in his researches
on atomic weights. The help to be derived from this law may be illustrated
thus: let us assume that two compounds have been obtained exhibiting
identity of crystalline form; let it be further assumed that the number of
elementary atoms in the atom of one of these compounds is known; it
follows, by the law of isomorphism, that the number of elementary atoms in
the atom of the other is known also. Let the two compounds be _sulphate of
potash_ and _chromate of potash_; let it be assumed that the atom of the
first named is known to consist of two atoms of potassium, one atom of
sulphur, and four atoms of oxygen; and that the second substance is known
to be a compound of the elements potassium, chromium and oxygen; then the
atom of the second compound contains, by Mitscherlich's law, two atoms of
potassium, one atom of chromium and four atoms of oxygen: hence the
relative weight of the atom of chromate of potash can be determined, and
hence the relative weight of the atom of chromium can also be determined.
A year after the announcement of Mitscherlich's law, the following
generalization was stated to hold good, by two French naturalists, Dulong
and Petit:--"The atoms of all solid elements have the same capacity for
heat."
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