Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
The fixity of composition of chemical compounds has now been established; a
definite meaning has been given to the term "element;" the conception of
"atom" has been gained, but much remains to be done in the way of rendering
this conception precise; and fairly good, but not altogether satisfactory
methods have been introduced by which the relative weights of the atoms of
elements and compounds may be determined. At this time chemists are busy
preparing and describing new compounds, and many new elements are also
being discovered; the need of classification begins to be felt more and
more.
In the days of Berzelius and Davy strenuous efforts were made to obtain
some generalizations by the application of which the many known elements
and compounds might be divided into groups. It was felt that a
classification might be founded on the composition of compounds, or perhaps
on the properties of the same compounds. These two general principles
served as guides in most of the researches then instituted; answers were
sought to these two questions: Of what elements is this compound composed?
and, What can this compound do; how does it react towards other bodies?
Lavoisier, as we know, regarded oxygen as the characteristic element of all
_acids_. This term _acid_ implies the possession, by all the substances
denoted by it, of some common property; let us shortly trace the history of
this word in chemistry.
Vinegar was known to the Greeks and Romans, and the names which they gave
this substance tell us that sourness was to them its characteristic
property. They knew that vinegar effervesced when brought into contact with
chalky earths, and that it was able to dissolve many substances--witness
the story of Cleopatra's draught of the pearl dissolved in vinegar. Other
substances possessed of these properties--for instance oil of vitriol and
spirits of salt--as they became known, were classed along with vinegar; but
no attempts were made to clearly define the properties of these bodies till
comparatively recent times.
The characteristics of an acid substance enumerated by Boyle are--solvent
power, which is exerted unequally on different bodies; power of turning
many vegetable blues to red, and of restoring many vegetable colours which
had been destroyed by alkalis; power of precipitating solid sulphur from
solutions of this substance in alkalis, and the power of acting on alkalis
to produce substances without the properties of either acid or alkali.
But what, one may ask, is an alkali, of which mention is so often made by
Boyle?
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