Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
If the amount of heat required to raise the temperature of one grain of
water through one degree be called _one unit of heat_, then the capacity
for heat of any body other than water is the number of units of heat
required to raise the temperature of one grain of that substance through
one degree. Each chemical substance, elementary and compound, has its own
capacity for heat; but, instead of comparing the capacities for heat of
equal weights, Dulong and Petit compared the capacities for heat of weights
representing the weights of the atoms of various elements. Thus, equal
amounts of heat are required to raise, through the same interval of
temperature, fifty-six grains of iron, one hundred and eight grains of
silver, and sixty-three and a half grains of copper; but the weights of the
atoms of these three elements are in the proportion of 56:108:63-1/2.
Dulong and Petit based their generalization on measurements of the
capacities for heat of thirteen elements; further research has shown that
their statement most probably holds good for all the solid elements. Here
then was a most important instrument put into the hands of the chemist.
It is only necessary that the atomic weight of one solid element should be
certainly known, and that the amount of heat required to raise through one
degree the number of grains of that element expressed by its atomic weight
should also be known; then the number which expresses the weight, in
grains, of any other solid element which is raised through one degree by
the same amount of heat, likewise expresses the relative weight of the atom
of that element. Thus, suppose that the atomic weight of silver is known to
be 108, and suppose that six units of heat are required to raise the
temperature of one hundred and eight grains of this metal through one
degree; then suppose it is found by experiment that six units of heat
suffice to raise the temperature of two hundred and ten grains of bismuth
through one degree, it follows--according to the law of Dulong and
Petit--that 210 is the atomic weight of bismuth.
The modified generalization of Gay-Lussac--"Equal volumes of _elementary_
gases contain equal numbers of atoms;" the laws of "isomorphism" and of
"atomic heat;" and the two empirical rules stated on p. 163;--these were
the guides used by Berzelius in interpreting the analytical results which
he and his pupils obtained in that memorable series of researches, whereby
the conceptions of Dalton were shown to be applicable to a wide range of
chemical phenomena.
Public-domain text, read in full here on John Shaqi.
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