Heroes of Science: ChemistsMuir, M. M. Pattison (Matthew Moncrieff Pattison)
History
Heroes of Science: Chemists
Muir, M. M. Pattison (Matthew Moncrieff Pattison)
Chemistry -- History; Chemists
We must note the appearance of the term _vitriol_, applied to the solid
salt-like bodies obtained from acids and characterized by a glassy lustre.
By the middle of last century the vitriols were recognized as all derived
from, or compounded of, sulphuric acid (oil of vitriol) and metals; this
led to a subdivision of the large class of neutral salts into (1) metallic
salts produced by the action of sulphuric acid on metals, and (2) neutral
salts produced by the action of earths or alkalis on acids generally.
To Rouelle, a predecessor of Lavoisier, who died four years before the
discovery of oxygen, we owe many accurate and suggestive remarks and
experiments bearing on the term "salt." I have already mentioned that it
was he who applied the word "base" to the alkali or earth, or it might be
metal, from which, by the action of acid, a salt is built up. He also
ceased to speak of an acid as _sal acidum_, or of an alkali as _sal
alkali_, and applied the term "salt" exclusively to those substances which
are produced by the action of acids on bases. When the product of such an
action was neutral--that is, had no sour taste, no soapy feeling to the
touch, no action on vegetable colours, and no action on acids or bases--he
called that product _a neutral salt_; when the product still exhibited some
of the properties of acid, _e.g._ sourness of taste, he called it _an acid
salt_; and when the product continued to exhibit some of the properties of
alkali, _e.g._ turned vegetable reds to blue, he called it _an alkaline
salt_.
Rouelle also proved experimentally that an acid salt contains more
acid--relatively to the same amount of base--than a neutral salt, and that
an alkaline salt contains more base--relatively to the same amount of
acid--than a neutral salt; and he proved that this excess of acid, or of
base, is chemically united to the rest of the salt--is, in other words, an
essential part of the salt, from which it cannot be removed without
changing the properties of the whole.
But we have not as yet got to know why certain qualities connoted by the
term "acid" can be affirmed to belong to a group of bodies, why certain
other, "alkaline," properties belong to another group, nor why a third
group can be distinguished from both of these by the possession of
properties which we sum up in the term "earthy." Surely there must be some
peculiarity in the composition of these substances, common to all, by
virtue of which all are acid. The atom of an acid is surely composed of
certain elements which are never found in the atom of an alkali or an
earth; or perhaps the difference lies in the number, rather than in the
nature of the elements in the acid atoms, or even in the arrangement of the
elementary atoms in the compound atom of acid, of alkali, and of earth.
Public-domain text, read in full here on John Shaqi.
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