The treatise on "The Spring of the Air" met with much opposition, and
Boyle considered it necessary to defend his doctrine against the
objections of Franciscus Linus and Hobbes. In this defence he
described the experiment in connection with which he is most generally
remembered. Linus had admitted that the air might possess a certain
small amount of elasticity, but maintained that the force with which
mercury rose in a barometer tube was due mainly to a totally different
action, as though a string were pulling upon it from above. This was
his funicular hypothesis. Boyle undertook to show that the pressure of
the air might be made to support a much higher column of mercury than
that of the barometer. To this end he took a glass tube several feet
in length, and bent so as to form two vertical legs connected below.
The shorter leg was little more than a foot long, and hermetically
closed at the top. The longer leg was nearly eight feet in length, and
open at the top. The tube was suspended by strings upon the staircase,
the bend at the bottom pressing lightly against the bottom of a box
placed to receive the mercury employed in case of accident. Each leg
of the tube was provided with a paper scale. Mercury was poured in at
the open end, the tube being tilted so as to allow some of the air to
escape from the shorter limb until the mercury stood at the same level
in both legs when the tube was vertical. The length of the closed tube
occupied by the air was then just twelve inches. The height of the
barometer was about 29-1/8 inches. Mercury was gently poured into the
open limb by one operator, while another watched its height in the
closed limb. The results of the experiments are given in the table on
the opposite page.
In this table the third column gives the result of adding to the
second column the height of the barometer, which expresses in inches
of mercury the pressure of the air on the free surface of the mercury
in the longer limb. The fourth column gives the total pressure, in
inches of mercury, on the hypothesis that the pressure of the air
varies inversely as the volume. The agreement between the third and
fourth columns is very close, considering the roughness of the
experiment and that no trouble appears to have been taken to
_calibrate_ the shorter limb of the tube, and justified Boyle in
concluding that the hypothesis referred to expresses the relation
between the volume and pressure of a given mass of air.
Public-domain text, read in full here on John Shaqi.
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